4957-24-8Relevant articles and documents
Chiral anion phase-transfer catalysis applied to the direct enantioselective fluorinative dearomatization of phenols
Phipps, Robert J.,Toste, F. Dean
supporting information, p. 1268 - 1271 (2013/03/14)
Chiral anion phase-transfer catalysis has enabled the direct and highly enantioselective fluorinative dearomatization of phenols catalyzed by a BINOL-derived phosphate. The process efficiently transforms simple, readily available phenols into fluorinated chiral small molecules bearing reactive functionality under ambient reaction conditions with high enantioselectivity. The close relationship of the products with well-studied o-quinols provides numerous avenues for synthetic elaboration and exciting opportunities for bioisosteric replacement of hydroxyl with fluorine in natural products.
Indan-5-yl-N-methylcarbamic acid esters
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, (2008/06/13)
Indan-5-yl-N-methylcarbamic acid esters of the formula STR1 in which R represents hydrogen or C1 -C4 alkyl, R1 represents hydrogen or C1 -C4 alkyl, R2 represents C1 -C4 alkyl, R3 represents hydrogen or C1 -C4 alkyl and R4 represents hydrogen, chlorine, bromine, C1 -C4 alkyl or C1 -C4 alkoxy, Which possess arthropodicidal and fungicidal properties.