474958-87-7

Basic information

• Product Name: (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-ol
• Synonyms: (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-ol
• CAS NO: 474958-87-7
• Molecular Weight: 248.322
• Mol File: 474958-87-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-ol(474958-87-7)
• EPA Substance Registry System: (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-ol(474958-87-7)

Safety Data

• Hazardous Substances Data: 474958-87-7(Hazardous Substances Data)

Upstream product

• 153481-85-7 (4R,5S)-2,2-dimethyl-5-phenyl-[1,3]-dioxolane-4-carbaldehyde 
• 1006371-16-9 (4R,5S)-2,2-dimethyl-4-[(2R)-oxiran-2-yl]-5-phenyl-1,3-dioxolane 
• 1826-67-1 vinyl magnesium bromide 

Downstream Products

• 1006371-17-0 (1R)-1-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]but-3-en-1-yl prop-2-enoate 
• 474958-89-9 (6R)-6-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]-5,6-dihydro-2H-pyran-2-one 
• 146236-73-9 (6R)-6-[(1R,2S)-1,2-dihydroxy-2-phenylethyl]-5,6-dihydro-2H-pyran-2-one 
• 136685-37-5 (1R,5R,7S,8S)-8-hydroxy-7-phenyl-2,6-dioxa-bicyclo-[3.3.1]-nonan-3-one 

Relevant articles and documents

Highly diastereoselective total syntheses of (+)-7-epigoniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone

An expedient concise total synthesis of (+)-7-epigoniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone is accomplished. The key transformations include a catalytic hydroxylation and base-mediated N-(acetyl)oxazolidinone addition reactions, which cou