461406-29-1Relevant articles and documents
Studies aimed at the total synthesis of azadirachtin. A modeled connection of C-8 and C-14 in azadirachtin
Fukuzaki, Takehiro,Kobayashi, Satoshi,Hibi, Takamasa,Ikuma, Yohei,Ishihara, Jun,Kanoh, Naoki,Murai, Akio
, p. 2877 - 2880 (2007/10/03)
(figure presented) Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid frame