4441-12-7 Usage
Description
Trimorpholinophosphine oxide, also known as morPO, is a chemical compound that plays a significant role in coordination chemistry, particularly in the formation of complexes with phosphoryl compounds. It is characterized by its ability to coordinate with various metal ions, making it a versatile ligand for creating stable and diverse metal complexes.
Uses
Used in Coordination Chemistry:
Trimorpholinophosphine oxide is used as a ligand in coordination chemistry for the formation of complexes with phosphoryl compounds. It forms complexes such as [Fe(morPO)nX2] (n = 1/2-4, X = BF4, NO3, NCS, Cl, Br, or I), where the ligand morPO is coordinated by the oxygen atom. This coordination ability allows for the exploration of various chemical and physical properties of these complexes, making morPO a valuable component in the study and development of new materials and catalysts.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, Trimorpholinophosphine oxide's coordination chemistry properties could potentially be applied in the pharmaceutical industry for the development of metal-based drugs or as a component in drug delivery systems. Its ability to form stable complexes with metal ions may contribute to the design of novel therapeutic agents or improve the efficacy and targeting of existing drugs.
Used in Catalyst Development:
Trimorpholinophosphine oxide's coordination chemistry properties can also be utilized in the development of catalysts for various chemical reactions. The complexes formed with morPO can potentially act as catalysts, enhancing the rate of reactions and improving the overall efficiency of chemical processes. This application can be particularly useful in industries such as petrochemicals,精细化工, and environmental remediation, where efficient catalysts are crucial for cost-effective and sustainable production processes.
Check Digit Verification of cas no
The CAS Registry Mumber 4441-12-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,4,4 and 1 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 4441-12:
(6*4)+(5*4)+(4*4)+(3*1)+(2*1)+(1*2)=67
67 % 10 = 7
So 4441-12-7 is a valid CAS Registry Number.
4441-12-7Relevant articles and documents
The first coordination compounds of OP[NC4H8O]3 phosphoric triamide ligand: structural study and Hirshfeld surface analysis of SnIV and MnII complexes
Pourayoubi, Mehrdad,Tarahhomi, Atekeh,Golen, James A.,Rheingold, Arnold L.
, p. 1285 - 1302 (2017)
The first X-ray crystal structures of coordination compounds of OP[NC4H8O]3 phosphoric triamide (L) are investigated in Cl2(CH3)2Sn(trans-L)2 (1) and [Mn(H2O)4(trans-L)2]Cl2·2H2O (2) as models of molecular and salt complexes for Hirshfeld surface (HS)-based analysis. The crystal packing of 1 includes weak interactions, while in the salt complex 2, a 2-D aggregate, along the (001) plane, is mediated by normal O–H?Cl and O–H?O hydrogen bonds. In the Hirshfeld study, the crystal cohesions of 1 and 2 are recognized via H?H, O?H/H?O, and Cl?H/H?Cl contacts. Among these interactions, hydrogen bonds O–H?Cl occur in the salt structure of 2, as well as some weaker hydrogen interactions as C–H?O (1 and 2), C–H?Cl (1), and O–H?O (2). The full fingerprint plots have nearly symmetric shapes for two independent molecules of 1, while an asymmetric shape appears for the cationic component of 2. To extract more detailed information on close intermolecular contacts, the molecular surface of the previously reported structure L was also mapped. The structure 2 is the first monomeric octahedral Mn(II)–phosphoric triamide complex reported so far. Furthermore, the HS analysis of 2 is the first such study on a cation–anion complex structure including phosphoric triamide ligand.
Investigations on synthesis, thermolysis, and coordination chemistry of aminophosphine oxides
Veerashekhar Goud,Pavan Kumar,Shruthi, Yacham,Paul, Arijitha,Sivaramakrishna, Akella,Vijayakrishna, Kari,Brahmananda Rao,Sabharwal,Clayton
, p. 2647 - 2658 (2014/02/14)
Some aminophosphine oxides (AmPOs), (R1)(R2)(R 3)P=O [R1=R2=R3= HNCH 2CH=CH2; R1= R2=Ph, R 3=HNCH2CH=CH2; R
