4314-19-6 Usage
Description
BIS(1-BENZOTRIAZOLYL)METHANETHIONE 97, also known as BBTM, is an organic compound with the chemical formula C11H10N4S2. It is a reagent commonly used in various chemical reactions and synthesis processes due to its unique properties and versatility.
Uses
Used in Chemical Synthesis:
BIS(1-BENZOTRIAZOLYL)METHANETHIONE 97 is used as a thioacylating agent for the synthesis of various organic compounds. Its ability to form thioacyl derivatives makes it a valuable tool in the development of new chemical entities.
Used in Multicomponent Heterocyclization Reactions:
In the field of heterocyclic chemistry, BBTM is employed as a reactant in multicomponent reactions, which are essential for the synthesis of complex heterocyclic structures with potential applications in pharmaceuticals, agrochemicals, and materials science.
Used in the Synthesis of Substituted Thiosemicarbazides and N-Hydroxythioureas:
BBTM is utilized in the preparation of substituted thiosemicarbazides and N-hydroxythioureas, which are important classes of compounds with diverse biological activities, including antimicrobial, antiviral, and anticancer properties.
Used in Guanylation of Amines:
BBTM is also used in the guanylation of amines, a reaction that involves the formation of guanidine derivatives. These compounds have a wide range of applications, including their use as pharmaceuticals, agrochemicals, and synthetic intermediates.
Check Digit Verification of cas no
The CAS Registry Mumber 4314-19-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,3,1 and 4 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 4314-19:
(6*4)+(5*3)+(4*1)+(3*4)+(2*1)+(1*9)=66
66 % 10 = 6
So 4314-19-6 is a valid CAS Registry Number.
InChI:InChI=1/C13H8N6S/c20-13(18-11-7-3-1-5-9(11)14-16-18)19-12-8-4-2-6-10(12)15-17-19/h1-8H
4314-19-6Relevant articles and documents
Urea and thiourea based anion receptors in solution and on polymer supports
Byrne,Mullen
, p. 196 - 205 (2017/11/08)
Herein we report the development of a new series of surface bound anion sensors exploiting the urea or thiourea motif capable of binding anions through hydrogen bonding interactions. The use of high resolution magic angle spinning 1H NMR allows the direct comparison of the anion binding properties of these receptors in solution versus those tethered to polymer resins. Some intramolecular hydrogen bonding and solvent effects were observed at the solution:surface interface however in general the anion binding properties of the polymer bound urea and thiourea receptors were maintained.
Trapping Reactive Intermediates by Mechanochemistry: Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents
?trukil, Vjekoslav,Gracin, Davor,Magdysyuk, Oxana V.,Dinnebier, Robert E.,Fri??ic, Tomislav
supporting information, p. 8440 - 8443 (2015/11/27)
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.
