425386-34-1Relevant articles and documents
Ni-Catalyzed Cyclization of Enynes and Alkynylboronates: Atom-Economical Synthesis of Boryl-1,4-dienes
Cabrera-Lobera, Natalia,Quirós, M. Teresa,Bu?uel, Elena,Cárdenas, Diego J.
, p. 14512 - 14516 (2019/11/11)
We report a novel atom-economical Ni-catalyzed cyclization reaction of enynes with alkynylboronates. The reaction employs a non-expensive Ni salt, a phosphine-based ligand and easy-handling alkynylboronates as boron–carbon source. The reaction provides co
Thioureas as ligands in the Pd-catalyzed intramolecular Pauson-Khand reaction
Tang, Yefeng,Deng, Lujiang,Zhang, Yangdong,Dong, Guangbin,Chen, Jiahua,Yang, Zhen
, p. 1657 - 1659 (2007/10/03)
(Chemical Equation Presented) The thiourea-Pd complex was established as a novel type of catalyst in the PKR of allylpropargylamine, and the demonstrated chemistry may prove to be valuable for developing thiuorea as a ligand for the Pd-catalyzed Pauson-Kh