40856-15-3Relevant articles and documents
Copper-catalyzed cyanation of alkenyl iodides
Nitelet, Antoine,Zahim, Sara,Theunissen, Cédric,Pradal, Alexandre,Evano, Gwilherm
, p. 163 - 177 (2017/03/06)
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Highly active ruthenium-based catalyst for metathesis of cyano-contained olefins
Zhang, Wenzhen,Zhang, Rong,He, Ren
, p. 4203 - 4205 (2008/02/05)
Ruthenium benzylidene complex (H2IMes)(2-CH3-C5H4N)(Cl)2Ru{double bond, long}CHPh [H2IMes = 1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] (4), which introduced ortho substituted pyridine as dissociating ligand to weaken Ru-N bond and accelerate initiation through steric hindrance, was prepared by the reaction of (H2IMes)(PPh3)(Cl)2Ru{double bond, long}CHPh (1) with 2-methylpyridine and proved to exhibit enhanced catalytic activity for cyano-contained olefin metathesis.
Indium(I) bromide-mediated coupling of dibromoacetonitrile with aldehydes followed by Boord elimination of bromine and oxygen of β-bromo alkoxides for preparation of 3-organyl-2-alkenenitriles
Peppe, Clovis,de Azevedo Mello, Paola,das Chagas, Rafael Pav?o
, p. 2335 - 2339 (2007/10/03)
The organoindium compound derived from indium monobromide and dibromoacetonitrile reacts with carbonyl compounds to afford the corresponding 2-bromo-2-cyano-indium(III) alkoxide. The action of a second equivalent of indium monobromide onto the alkoxides derived from aldehydes promotes the Boord elimination of the β-related oxygen and bromine atoms leading to 2-alkenenitriles.
