39860-72-5

Basic information

• Product Name: N-benzyl-4-(benzyloxy)aniline
• Synonyms: N-benzyl-4-(benzyloxy)aniline
• CAS NO: 39860-72-5
• Molecular Weight: 289.377
• Mol File: 39860-72-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-benzyl-4-(benzyloxy)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-4-(benzyloxy)aniline(39860-72-5)
• EPA Substance Registry System: N-benzyl-4-(benzyloxy)aniline(39860-72-5)

Safety Data

• Hazardous Substances Data: 39860-72-5(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 6373-46-2 p-benzyloxyaniline 
• 94040-95-6 1-azido-4-(benzyloxy)benzene 
• 6554-98-9 trans-4-Hydroxystilbene 
• 1145-76-2 benzyl 4-nitrophenyl ether 
• 385446-23-1 N-(4-(benzyloxy)phenyl)-1-phenylmethanimine 

Relevant articles and documents

Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C=C Bond Cleavage

C=C bond breaking to access the C=N bond remains an underdeveloped area. A new protocol for C=C bond cleavage of alkenes under nonoxidative conditions to produce imines via an iron-catalyzed nitrene transfer reaction of 4-hydroxystilbenes with aryl azides is reported. The success of various sequential one-pot reactions reveals that the good compatibility of this method makes it very attractive for synthetic applications. On the basis of experimental observations, a plausible reaction mechanism is also proposed.

Mild and efficient PtO2-catalyzed one-pot reductive mono-N-alkylation of nitroarenes

(Chemical Equation Presented) A mild and efficient one-pot reductive monoalkylation of nitroarenes has been described using aldehydes as alkylating agents, molecular hydrogen as a reducing agent, and PtO2 as a catalyst in methanol. This methodology is found to be applicable for both aliphatic and aromatic aldehydes and for a wide variety of nitroarenes. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Commuications to view the free supplemental file. Copyright Taylor & Francis Group, LLC.