39389-20-3

Basic information

• Product Name: AMBERLYST(R) 15
• Synonyms: amberlyst15ion-exchangeresin;Benzenesulfonicacid,ethenyl-,polymerwithdiethenylbenzene;ethenyl-benzenesulfonicacipolymerwithdiethenylbenzene;AMBERLYST(TM) 15 (H);AMBERJET(R) 1200 HYDROGEN FORM;'AMBERJET' 1200NA;AMBERLYST 15;'AMBERLYST' 15
• CAS NO: 39389-20-3
• Molecular Formula: C18H18O3S
• Molecular Weight: 314.39872
• Product Categories: Polymers;Amberlite Strong Cation ExchangersLPLC Separation Media;Amberlite&AmberchromResins&LC Separation Media;Amberlite(R);Adsorbent Media (Polymeric);Cation;Cation Exchange Media;Resins&LC Separation Media;Amberlite;Anion;LPLC Separation Media
• Mol File: 39389-20-3.mol
• Article Data: 0

Chemical Properties

• Boiling Point: 516.7°Cat760mmHg
• Flash Point: 266.3°C
• Appearance: Pale brown/Beads
• Density: 1.2 g/mL at 25 °C(lit.)
• Vapor Density: >1 (vs air)
• Vapor Pressure: 1.68E-11mmHg at 25°C
• Water Solubility: Insoluble in water.
• Sensitive: Hygroscopic
• CAS DataBase Reference: AMBERLYST(R) 15(CAS DataBase Reference)
• NIST Chemistry Reference: AMBERLYST(R) 15(39389-20-3)
• EPA Substance Registry System: AMBERLYST(R) 15(39389-20-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26-36
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 39389-20-3(Hazardous Substances Data)

Usage

Description

AMBERLYST(R) 15 is a strongly acidic cation exchange resin, characterized by its heterogeneous acid catalysis properties. This unique feature makes it particularly suitable for non-aqueous catalysis applications, offering a versatile and efficient catalyst for a wide range of chemical reactions.

Uses

Used in Chemical Reactions:
AMBERLYST(R) 15 is used as a catalyst for various chemical reactions, including esterification, transesterification, Michael addition, Prins cyclization, Friedel-Crafts alkylation, acylation, cleavage of epoxides, and crossed-aldol condensation. Its strong acidity and non-aqueous compatibility make it a preferred choice for accelerating reaction rates and enhancing product yields.
Used in Analytical Chemistry:
AMBERLYST(R) 15 is utilized as a column packing material for High-Performance Liquid Chromatography (HPLC) analysis. Its strong acidic nature and ion exchange capabilities contribute to the efficient separation and identification of compounds in complex mixtures.
Used in Separation Media:
In the field of chromatography, AMBERLYST(R) 15 is employed in separation media for Thin-layer chromatography (TLC) and paper chromatography. Its ability to selectively interact with various compounds based on their charge and polarity allows for effective separation and purification processes.
Used in Mechanistic Studies:
AMBERLYST(R) 15 is used to determine the mechanism of phenol alkylation using density functional theory (DFT). This application highlights its role in understanding reaction pathways and providing insights into the fundamental aspects of chemical reactions, which can be crucial for optimizing reaction conditions and developing new synthetic strategies.

InChI:InChI=1/C10H10.C8H8O3S/c1-3-9-7-5-6-8-10(9)4-2;1-2-7-5-3-4-6-8(7)12(9,10)11/h3-8H,1-2H2;2-6H,1H2,(H,9,10,11)