39032-08-1

Basic information

• Product Name: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-acetoxyphenethoxy)tetrahydro-2Hpyran-3,4,5-triyl triacetate
• Synonyms: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-acetoxyphenethoxy)tetrahydro-2Hpyran-3,4,5-triyl triacetate
• CAS NO: 39032-08-1
• Molecular Weight: 510.495
• Mol File: 39032-08-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-acetoxyphenethoxy)tetrahydro-2Hpyran-3,4,5-triyl triacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-acetoxyphenethoxy)tetrahydro-2Hpyran-3,4,5-triyl triacetate(39032-08-1)
• EPA Substance Registry System: (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-acetoxyphenethoxy)tetrahydro-2Hpyran-3,4,5-triyl triacetate(39032-08-1)

Safety Data

• Hazardous Substances Data: 39032-08-1(Hazardous Substances Data)

Upstream product

• 60037-43-6 2-(4-acetoxyphenyl)ethanol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 38177-33-2 (4-acetoxyphenyl)acetic acid 
• 156-38-7 4-hydroxyphenylacetate 
• 824-94-2 p-methoxybenzyl chloride 
• 14199-15-6 Methyl 4-hydroxyphenylacetate 
• 501-94-0 p-hydroxyphenethyl alcohol 
• 104-01-8 4-Methoxyphenylacetic acid 
• 6919-96-6 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 

Downstream Products

• 123563-44-0 rengyoside B 
• 40593-03-1 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-[2-(1-hydroxy-4-oxo-cyclohexa-2,5-dienyl)-ethoxy]-tetrahydro-pyran-4-yl ester 
• 40661-45-8 cornoside 
• 28251-63-0 tetraacetyl salidroside 
• 10338-51-9 Salidroside 

Relevant articles and documents

Preparation method of natural product salidroside

The invention provides a new method for total synthesis preparation of salidroside. The method is characterized by comprising the following steps: reacting glucose pentaacetate (I) with 4-acetoxy phenethyl alcohol (II) in an organic solvent under the catalysis of a catalyst MXbLc to obtain 2-(4-acetoxyphenyl)-ethyl-(2,3,4,6-O-tetraacetyl)-beta-D-glucopyranoside (III); and performing deacetylation protection on the 2-(4-acetoxyphenyl)-ethyl-(2,3,4,6-O-tetraacetyl)-beta-D-glucopyranoside (III) to obtain salidroside.

Synthesis of 13C-labeled possible intermediates in the biosynthesis of phenylethanoid derivatives, cornoside and rengyosides

In order to clarify the biosynthetic pathway of C6-C2 unit compounds containing salidroside, cornoside, and rengyosides A and B in oleaceous plants, 13C-labeled putative precursors, 4-hydroxyphenylethanol, salidroside and cornoside, were prepared.