38834-26-3Relevant articles and documents
The reactions of AgY salts with 4-n(CNMe)n> complexes (Y(1-) = NO3(1-), BF4(1-) or PF6(1-); n = 0, 1 or 2). The crystal structure of BF4
Callan, Brian,Manning, A. R.,Stephens, F. S.
, p. 357 - 378 (2007/10/02)
The oxidative cleavage of 4-n(CNMe)n> (n = 0 - 2) by 2AgX gives mononuclear products.It is shown to be a two-electron process in most solvents but a one-electron process in acetonitrile.The two-electron oxidations proceed by way of adducts such as >BF4 which are isolable when n = 2, detectable when n = 1 and postulated when n = 0.The one-electron process gives no adducts, and 1AgX cleaves all of the substrate to (1+) and . (L = CO or CNMe).The latter may combine or react with added CHBr3 to give .The structure of BF4 has been determined by X-ray diffraction.
BIMETALLIC ACTIVATION OF COORDINATED LIGANDS. REACTIONS OF THE LEWIS ACID (η-C5H5)(CO)3Mo+ PF6- WITH ORGANO-IRON AND -MOLYBDENUM η1-METHOXYMETHYL AND ETHYL COMPLEXES
Markham, James,Tolman, William,Menard, Kevin,Cutler, Alan
, p. 45 - 58 (2007/10/02)
The organometallic Lewis acid Cp(CO)3Mo+ PF6- reacts with organo-iron and -molybdenum methoxymethyl and ethyl complexes via methoxide and/or hydride abstraction.Thus, Cp(CO)3MoCH2OCH3 and Cp(CO)(L)FeCH2OCH3 (L = CO, PPh3) produce the