381686-06-2Relevant articles and documents
Total synthesis of two isoflavone C-glycosides: genistein and orobol 8-C-β-d-glucopyranosides
Sato, Shingo,Hiroe, Kaoru,Kumazawa, Toshihiro,Jun-ichi, Onodera
, p. 1091 - 1095 (2007/10/03)
Genistein and orobol 8-C-β-d-glucopyranosides (1 and 3) were firstly synthesized in overall yields of 39% and 41% from 2,4-di-O-benzylphloroacetophenone (4), as follows: (1) the formation of the chalcone (6, 7) by aldol condensation of the benzyl-protecte