3585-33-9Relevant articles and documents
Evaluation of Amino Substituants as Nucleofugal Controllers of Regioselectivity and as Chelate Modulators of Stereoselectivity in Squarate Ester Cascades
Paquette, Leo A.,Kuo, Lung Huang,Tae, Jinsung
, p. 2010 - 2021 (1998)
The tandem addition of an alkenyllithium reagent and a 2-lithioallylamine to squarate esters has been systematically examined. The effect of the sequencing of this twofold addition has been investigated. The extent to which the amino group is eliminated was found to be dependent on the structural features of the companion nucleophile. Also assessed was the comparative ease with which the amino and methoxy groups experience competitive β-elimination from the highly reactive, medium-ring dianionic intermediates. Attempts were made to curtail the level of competing 1,4-addition, and success was achieved by increasing the effective size of the O-alkyl groups in the squarate ester. The highly stereocontrolled transformations described represent a notably direct means for producing highly fused polycyclic compounds. Mechanistic considerations surrounding these reactions, which are characterized by an impressive enhancement of molecular scaffolding, are discussed.
A nickel(II) guanidinate compound and its potential as CVD precursor for nickel related films
Zhang, Yuxiang,Du, Liyong,Liu, Xinfang,Ding, Yuqiang
, p. 218 - 222 (2018)
In this study, a nickel(II) compound with guanidinate ligand of the general form [((Me)2NC(iPrN)2)2Ni] has been synthesized and isolated from the reaction of NiCl2 with the corresponding lithium salt of guanidinate ligand [(Me)2NC(iPrN)2Li] at 70 °C. Its structure was determined by 1H NMR, elemental analysis, and single crystal X-ray diffraction. Thermogravimetric analysis (TGA) was employed to study the thermal properties (including thermal stability, volatility, vapor pressure and transport behavior) of compound. Furthermore, a deposition experiment was made to examine the compound's potential as CVD precursor, and a Ni metal film was successfully deposited. These preliminary results illustrate the potential of this compound to act as CVD precursor.
Fabrication and characterization of ALD-grown ZrO2:Ge thin films on Si(100) using CpZr(NMe2)3 and (NMe2)2Ge(ipr2en) precursors with ozone
Jung, Jae-Sun,Kim, Dae-Hyun,Shin, Jin-Ho,Kang, Jung-Soo,Thomas, Joseph P.,Leung,Kang, Jun-Gill
, p. 2162 - 2165 (2015/08/18)
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