35843-79-9

Basic information

• Product Name: Benzene, (6-chloro-1-hexynyl)-
• CAS NO: 35843-79-9
• Molecular Formula: C12H13Cl
• Molecular Weight: 192.688
• Mol File: 35843-79-9.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, (6-chloro-1-hexynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (6-chloro-1-hexynyl)-(35843-79-9)
• EPA Substance Registry System: Benzene, (6-chloro-1-hexynyl)-(35843-79-9)

Safety Data

• Hazardous Substances Data: 35843-79-9(Hazardous Substances Data)

Upstream product

• 112403-39-1 (4-chlorobutyl)zinc iodide 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 20999-32-0 4-chlorobutyl 4-methylbenzenesulfonate 
• 4440-01-1 lithium phenylacetylide 
• 110-56-5 1,4-dichlorobutane 
• 6940-78-9 4-chlorobutyl bromide 
• 591-50-4 iodobenzene 
• 10297-06-0 1-chloro-5-hexyne 
• 108-86-1 bromobenzene 
• 69936-53-4 6-phenylhex-5-yn-1-ol 
• 928-90-5 5-hexyl-1-ol 
• 103935-55-3 4-chlorobutanol-1-trifluoromethanesulfonate 
• 536-74-3 phenylacetylene 

Downstream Products

• 95018-41-0 2-benzyl-3,4,5,6-tetrahydropyridine 
• 856120-87-1 (6-azidohex-1-yn-1-yl)benzene 

Relevant articles and documents

Ru-catalysed C(sp2)-H vinylation/annulation of benzoic acids and alkynes: rapid access to medium-sized lactones

An unprecedented ruthenium catalysed [4+4] annulation of readily available benzoic acids and alkynes is reported for the first time. The carboxylate group acts as both a directing group and an internal nucleophilic reagent to facilitate a C(sp2

A Commercially Available and User-Friendly Catalyst for Hydroamination Reactions under Technical Conditions

The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalyst was also found active in intermolecular aza-Michael reactions.

Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2

A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO2 at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.