35519-24-5Relevant articles and documents
Chemoselective Synthesis of Z-Olefins through Rh-Catalyzed Formate-Mediated 1,6-Reduction
Dada, Raphael,Wei, Zhongyu,Gui, Ruohua,Lundgren, Rylan J.
supporting information, p. 3981 - 3984 (2018/03/21)
Z-olefins are important functional units in synthetic chemistry; their preparation has thus received considerable attention. Many prevailing methods for cis-olefination are complicated by the presence of multiple unsaturated units or electrophilic functio
The use of radical decarboxylation in the preparation of 1-methylcarbapenem antibiotic precursors from D-glucosamine
Anaya,Barton,Cruz Caballero,Gero,Grande,Laso,Hernando
, p. 2137 - 2140 (2007/10/02)
The stereocontrolled synthesis of optically active 1-methylcarbapenams has been performed by radical cyclization and radical decarboxylation. 1,3,4-Trisubstituted 2-azetidinones, prepared by the Staudinger reaction with D-glucosamine as chiral auxiliary and sorbic acid were used as starting materials.