3517-90-6

Basic information

• Product Name: 4-METHOXYPHENYLMETHYLSULFONE
• Synonyms: 4-METHOXYPHENYLMETHYLSULFONE;1-METHANESULFONYL-4-METHOXY-BENZENE;4-methoxyphenyl methyl sulphone;NSC87355;1-(Methylsulfonyl)-4-methoxybenzene;1-Methoxy-4-(methylsulfonyl)benzene;1-Methoxy-4-methylsulfonylbenzene;4-Methoxy-1-(methylsulfonyl)benzene
• CAS NO: 3517-90-6
• Molecular Formula: C₈H₁₀O₃S
• Molecular Weight: 186.23
• Mol File: 3517-90-6.mol
• Article Data: 202

Chemical Properties

• Melting Point: 120-121.5°C
• Boiling Point: 341.1 °C at 760 mmHg
• Flash Point: 160.1 °C
• Appearance: /
• Density: 1.199 g/cm³
• Vapor Pressure: 0.000163mmHg at 25°C
• Refractive Index: 1.511
• Storage Temp.: Room temperature.
• CAS DataBase Reference: 4-METHOXYPHENYLMETHYLSULFONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXYPHENYLMETHYLSULFONE(3517-90-6)
• EPA Substance Registry System: 4-METHOXYPHENYLMETHYLSULFONE(3517-90-6)

Safety Data

• Hazardous Substances Data: 3517-90-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 28, p. 1945, 1963 DOI: 10.1021/jo01042a536

InChI:InChI=1/C8H10O3S/c1-11-7-3-5-8(6-4-7)12(2,9)10/h3-6H,1-2H3

Upstream product

• 3517-99-5 1-methoxy-4-(methylsulfinyl)benzene 
• 30541-56-1 adamantylidene-adamantane 
• 100-66-3 methoxybenzene 
• 7143-01-3 Methanesulfonic anhydride 
• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 
• 22821-86-9 1,4-bis(methanesulfonyl)benzene 
• 74-88-4 methyl iodide 
• 93-59-4 Perbenzoic acid 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 6462-31-3 methyl 2,4,6-trimethylphenyl sulfone 
• 132102-78-4 diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide 
• 3466-32-8 4-bromoohenyl methyl sulfone 
• 38050-71-4 9-methoxy-9-BBN 
• 1129-26-6 4-methoxybenzene sulfonamide 

Downstream Products

• 14763-60-1 4-methanesulfonyl-phenol 
• 132102-78-4 diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide 
• 1047974-45-7 (E)-1-(4-methoxyphenylsulfonyl)-4-phenylbut-3-en-2-ol 
• 108545-54-6 1-methoxy-4-((4-methylbenzyl)sulfonyl)benzene 
• 108485-22-9 1-((bromomethyl)sulfonyl)-4-methoxybenzene 
• 203247-70-5 1-methoxy-4-(phenethylsulfonyl)benzene 
• 14223-10-0 1-(benzylsulfonyl)-4-methoxybenzene 

Relevant articles and documents

High Chemoselectivity in the Construction of Aryl Methyl Sulfones via an Unexpected C-S Bond Formation between Sulfonylhydrazides and Dimethyl Phosphite

A highly chemoselective route to aryl methyl sulfones via an unexpected C S bond formation between sulfonylhydrazides and dimethyl phosphite catalyzed by NaI under mild conditions has been established. This transformation provides an alternative and metal-free pathway to acquire various aryl methyl sulfones in good to excellent yields. Notably, dimethyl phosphite was employed as a stable and readily available alkyl source.

Self-Assembled Polyoxometalate-Based Metal-Organic Polyhedra as an Effective Heterogeneous Catalyst for Oxidation of Sulfide

Two polyoxovanadate-based metal-organic polyhedra with octahedral (oct) and rhombic dodecahedral (rdo) geometries have been constructed from a concave molecular building block and linear and triangular carboxylate ligands. VMOP-7 is constructed from {V5O9Cl} SBU and a linear anthracene-9,10-dicarboxylic acid ligand in which all the anthracene groups are perpendicular to the edge of the octahedron. Such an arrangement mode can effectively reduce the steric hindrance between ligands. VMOP-8 is constructed from {V5O9Cl} SBU and a triangular biphenyl 3,4,5-tricarboxylate ligand, which exhibits an elongated rhombic dodecahedral configuration due to the geometry of the ligand. Furthermore, VMOP-8 can serve as a heterogeneous catalyst and exhibits efficient and common catalytic activity for oxidative desulfurization.

Assembly of polyoxometalate-thiacalix[4]arene-based inorganic-organic hybrids as efficient catalytic oxidation desulfurization catalysts

Self-assembly of polyoxometalates, Ni(ii)/Ag(i) cations and tetra-[5-(mercapto)-1-methyltetrazole]-thiacalix[4]arene (L) yielded three inorganic-organic hybrids, namely, [Ni3L2(CH3OH)6(H2O)4][PMo12O40]2·3CH3OH·2H2O (1), [Ni3L2(CH3OH)6(H2O)4][PW12O40]2·3CH3OH·2H2O (2) and [Ag3L(PMo12O40)] (3). In hybrids (1) and (2), Ni(ii) cations are linked by L ligands to produce layered frameworks, and H bonds among the [PMo12O40]3?/[PW12O40]3?anions and L ligands lengthen the structures to form 3D supramolecular architectures. Hybrid (3) exhibits a 3D architecture, of which Ag(i) cations not only coordinated with the N and O atoms of L ligands and [PMo12O40]3?anions simultaneously, but also connected each other by Ag-Ag interactions. It is worth mentioning that1and3as recyclable catalysts show excellent heterogeneous catalytic activity in oxidation desulfurization reactions.