3468-63-1Relevant articles and documents
A quantitative one-pot synthesis method for industrial azo pigments with recyclable wastewater
Feng, Guangyuan,Zhu, Meiling,Liu, Lei,Li, Chunbao
supporting information, p. 1769 - 1776 (2019/04/08)
Most industrial azo pigments are synthesized by diazotization in one pot and then coupling in another. This two-pot process has been transformed into a one-pot method by adding granular PTFE (polytetrafluoroethylene) to a mechanically agitated aqueous mixture of NaNO2, HCl, a diazo component and a coupling component. This method avoids the step of using a base or a surfactant to dissolve the coupling component. The reactions were fast and quantitative. The granular PTFE, wastewater and excess HCl were then reused 11 times without deteriorating the reaction rate and product purity. Altogether, 22 industrial pigments and 3 azo compounds were synthesized and the reaction can produce up to 22.7 g of product in the laboratory. Some reactions require less than 2 equiv. of HCl and a mechanism explaining this is proposed. In addition, an o-nitro group effect is advanced to explain the differences in coupling reaction rates for o-, m- and p-nitroaniline.
Disperse scarlet dye compound, preparation method therefor and application of disperse scarlet dye compound
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Paragraph 0039; 0041; 0042; 0043; 0045, (2019/01/05)
The invention discloses a disperse scarlet dye compound, a preparation method therefor and an application of the disperse scarlet dye compound. The disperse scarlet dye compound has a structure represented by a formula (I) shown in the description, wherein R is alkyl, alkoxy, halogen, nitro, cyano, a formula shown in the description or -OCH2CH=CH2. The invention provides the application of the disperse scarlet dye compound in printing and dyeing of hydrophobic textile materials. The disperse scarlet dye compound is bright-colored and beautiful in color and luster and has excellent washing fastness and sublimation fastness.