32651-37-9Relevant articles and documents
Palladium(II)-catalysed Oxidative Ring Cleavage of Cyclic Acetals with t-Butyl Hydroperoxide: Preparation of Monoesters of Diols
Hosokawa, Takahiro,Imada, Yasushi,Murahashi, Shun-Ichi
, p. 1245 - 1246 (1983)
Reaction of five- and six-membered cyclic acetals with tBuOOH in the presence of palladium(II) catalyst gives monoesters of diols in good yields.
Copper-catalyzed enantioselective synthesis of bridged bicyclic ketals from 1,1-disubstituted-4-methylene-1,6-hexanediols and related alkenols
Burde, Ameya S.,Karyakarte, Shuklendu D.,Sylvester, Eric D.,Chemler, Sherry R.
supporting information, p. 105 - 108 (2021/01/14)
Bridged bicyclic ketals display a range of bioactivities. Their catalytic enantioselective synthesis from acyclic 1,1-disubstituted alkene diols is disclosed. This reaction combines asymmetric catalysis with a distal radical migration. Alkynes and arenes
Electrochemical esterification reaction of alkynes with diols: Via cleavage of carbon-carbon triple bonds without catalyst and oxidant
Cheng, Hui-Hui,Gao, Hui,Li, Pin-Hua,Shen, Hui-Zhi,Wang, Pei-Long
supporting information, p. 6783 - 6791 (2020/11/09)
A novel electrochemical esterification of alkynes for the synthesis of esters was developed in which diols and their derivatives were used as the partners. This method is green as it is catalyst-free, oxidant-free, and additive-free and shows atom-economy. This is the first example of an electrochemical reaction via cleavage of carbon-carbon triple bonds. Meanwhile, this is also the first example of a carbon-carbon triple bond cleavage reaction of alkynes with diols. This journal is
