3261-60-7

Basic information

• Product Name: N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine
• Synonyms: N-(p-Methoxybenzylidene)-p-methoxybenzylamine;N-(4-Methoxybenzyl)-4-methoxybenzenemethanimine;N-(4-Methoxybenzylidene)-4-methoxybenzenemethanamine;N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine
• CAS NO: 3261-60-7
• Molecular Formula: C₁₆H₁₇NO₂
• Molecular Weight: 255.31
• Mol File: 3261-60-7.mol
• Article Data: 193

Chemical Properties

• Melting Point: 37-38 °C
• Boiling Point: 125 °C(Press: 14 Torr)
• Appearance: /
• Density: 1.02±0.1 g/cm3(Predicted)
• PKA: 5.28±0.50(Predicted)
• CAS DataBase Reference: N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine(3261-60-7)
• EPA Substance Registry System: N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine(3261-60-7)

Safety Data

• Hazardous Substances Data: 3261-60-7(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 2393-23-9 4-methoxy-benzylamine 
• 105-13-5 4-Methoxybenzyl alcohol 
• 100-46-9 benzylamine 
• 100-51-6 benzyl alcohol 
• 70978-37-9 1-(azidomethyl)-4-methoxybenzene 
• 124-38-9 carbon dioxide 
• 27318-90-7 1,10-phenanthroline-5,6-dione 
• 874-90-8 4-methoxybenzonitrile 
• 618-36-0 rac-methylbenzylamine 
• 2746-25-0 p-Methoxybenzyl bromide 
• 14429-02-8 benzyl-(4-methoxybenzyl)amine 
• 17061-62-0 N,N-bis(p-methoxybenzyl)amine 
• 62-53-3 aniline 

Downstream Products

• 1037299-28-7 C₁₈H₁₇F₂NO₃ 
• 2620-81-7 2-(4-methoxyphenyl)-1H-benzimidazole 
• 17061-62-0 N,N-bis(p-methoxybenzyl)amine 
• 5395-56-2 (E)-2-(2-(4-methoxyphenyl)vinyl)quinoline 
• 2620-83-9 1-(4-methoxybenzyl)-2-(4-methoxyphenyl)-1H-benzimidazole 

Relevant articles and documents

A Carbazolyl Porphyrin-Based Conjugated Microporous Polymer for Metal-Free Photocatalytic Aerobic Oxidation Reactions

Herein, a carbazolyl porphyrin-based π-conjugated microporous polymer was prepared via simple FeCl3-catalyzed oxidative polymerization. The resulting polymer (TCPP-CMP) exhibits high surface area, permanent pores, good stability, broad light absorption range and suitable redox potentials. As expected, TCPP-CMP is a highly effective metal-free and heterogeneous photocatalyst for a variety of aerobic oxidation reactions, including oxidative coupling of primary amines, oxidative dehydrogenation of secondary amines, and oxidation of sulfides into sulfoxides using molecular oxygen under visible light irradiation. Importantly, natural sunlight is able to promote the aerobic oxidation of benzylamine and thioanisole via TCPP-CMP photocatalyst with high conversion and selectivity, which are comparable with reactions conducted under artificial light. In addition, heterogeneous TCPP-CMP has good recyclability, which retained its activity even after four cycles. The current work lays the foundation for future applications of TCPP-CMP as metal-free heterogeneous photocatalyst for aerobic oxidation reactions.

Visible-light-responsive lanthanide coordination polymers for highly efficient photocatalytic aerobic oxidation of amines and thiols

Development of visible-light-induced photocatalytic reactions using molecular oxygen as the terminal oxidant is intriguing in view of the current environmental and energy issues. We report herein the synthesis and characterization of a series of novel pho

Cyclometalated Half-Sandwich Iridium(III) Complexes: Synthesis, Structure, and Diverse Catalytic Activity in Imine Synthesis Using Air as the Oxidant

Four air-stable cyclometalated half-sandwich iridium complexes 1-4 with C,N-donor Schiff base ligands were prepared through C-H activation in moderate-to-good yields. These complexes have been well characterized, and their exact structure was elaborated on by single-crystal X-ray analysis. The iridium(III) complexes 1-4 showed good catalytic activity in the imine synthesis under open-flask conditions (air as the oxidant) from primary amine oxidative homocoupling, secondary amine dehydrogenation, and the cross-coupling reaction of amine and alcohol. Substituents bonded on the ligands of the iridium complexes displayed little effect on the catalytic efficiency. The stability and good catalytic efficiency of the iridium catalysts, mild reaction conditions, and substrate universality showed their potential application in industrial production.