31582-29-3

Basic information

• Product Name: 2-Pyridineethanamine, N-(phenylmethyl)-N-[2-(2-pyridinyl)ethyl]-
• CAS NO: 31582-29-3
• Molecular Formula: C21H23N3
• Molecular Weight: 317.42700
• Mol File: 31582-29-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Pyridineethanamine, N-(phenylmethyl)-N-[2-(2-pyridinyl)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridineethanamine, N-(phenylmethyl)-N-[2-(2-pyridinyl)ethyl]-(31582-29-3)
• EPA Substance Registry System: 2-Pyridineethanamine, N-(phenylmethyl)-N-[2-(2-pyridinyl)ethyl]-(31582-29-3)

Safety Data

• Hazardous Substances Data: 31582-29-3(Hazardous Substances Data)

Upstream product

• 15496-36-3 bis[2-(2-pyridyl)ethyl]amine 
• 100-52-7 benzaldehyde 
• 103-74-2 2-(2-Hydroxyethyl)pyridine 
• 100-69-6 2-vinylpyridine 
• 100-46-9 benzylamine 
• 100-39-0 benzyl bromide 
• 109-06-8 α-picoline 
• 100-42-5 styrene 

Downstream Products

• 88326-42-5 Cu⁽¹⁺⁾*C₆H₅CH₂N(CH₂CH₂C₅H₄N)2*PF₆^(1-)=Cu(C₆H₅CH₂N(CH₂CH₂C₅H₄N)2)PF₆ 
• 88326-42-5 {Cu(benzyl-bis(2-pyridylethyl)amine)}PF₆ 
• 138026-50-3 aqua(N,N-bis{2-(2-pyridyl)ethyl}benzylamine)bis(trifluoromethanesulfonato)nickel(II) 

Relevant articles and documents

Pyridine Nucleus Hydroxylation with Copper Oxygenase Models

Reaction of iodosylbenzene with CuI complexes (2a,b) occurs with hydroxylation in the ortho position of one pyridine nucleus; CuIII=O species are postulated.

Benzylic ligand hydroxylation starting from a dicopper μ- I·2:I·2 peroxo intermediate: Dramatic acceleration of the reaction by hydrogen-atom donors

Radicals in directed pathways: The μ-I·2: I·2 peroxo CuII2 intermediate 1 shows a much faster benzylic ligand hydroxylation than systems without phenol. This novel reactivity can be further accelerated by addition of external H-atom donors such as TEMPO-H. The results imply initial H-atom transfer leading to the formation of phenoxyl radicals. A highly reactive copper oxyl intermediate is then formed, which inserts oxygen into the benzylic C-H bond. Copyright