30932-67-3

Basic information

• Product Name: methyl 2-(N,N-dimethylureido)-benzoate
• Synonyms: methyl 2-(N,N-dimethylureido)-benzoate
• CAS NO: 30932-67-3
• Molecular Weight: 222.244
• Mol File: 30932-67-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-(N,N-dimethylureido)-benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(N,N-dimethylureido)-benzoate(30932-67-3)
• EPA Substance Registry System: methyl 2-(N,N-dimethylureido)-benzoate(30932-67-3)

Safety Data

• Hazardous Substances Data: 30932-67-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 101-42-8 fenuron 
• 79860-05-2 2-dimethylammonio-(4H)-3,1-benzoxazine-4-one chloride 

Relevant articles and documents

Room-temperature palladium-catalyzed C-H activation: Ortho-carbonylation of aniline derivatives

Pd and CO - ureally got me! The title reaction proceeds efficiently at 18°C under CO (1 atm) with 5 % [Pd(OTs)2 (MeCN)2] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4-toluenesulfonyl).