30805-06-2Relevant articles and documents
Photochemistry of 2-azido-4,6-dichloro-s-triazine: Matrix isolation of a strained cyclic carbodiimide containing four nitrogen atoms in a seven-membered ring
Bucher, Goetz,Siegler, Fred,Wolff, J. Jens
, p. 2113 - 2114 (1999)
2-Azido-4,6-dichloro-s-triazine, matrix-isolated in Ar at 10 K, yields triplet nitrene and the strained cyclic carbodiimide upon photolysis.
REACTIVITY-IMPARTING COMPOUND, MANUFACTURING METHOD THEREOF, SURFACE REACTIVE SOLID USING REACTIVITY-IMPARTING COMPOUND, AND METHOD FOR MANUFACTURING SURFACE REACTIVE SOLID
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Paragraph 0048-0049, (2020/10/16)
PROBLEM TO BE SOLVED: To provide a reactivity-imparting compound that imparts reactivity enabling bonding between a solid and another material, wherein the reactivity-imparting compound can impart reactivity to the solid with high efficiency and wherein the bonding adhesion between the solid and another material is high, and to provide a method for manufacturing the same, a surface reactive solid using the same, and a method for manufacturing surface reactive solid. SOLUTION: There is provided a reactivity-imparting compound provided on a surface of a solid in order to bond between the solid and another material, wherein the reactivity-imparting compound is a compound having a triazine ring, an alkoxysilyl group (also including a case where an alkoxy group in the alkoxysilyl group is OH) and a diazomethyl group in one molecule. There are also provided a method for manufacturing the reactivity-imparting compound, a surface reactive solid using the same, and a method for manufacturing the surface reactive solid. SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2020,JPOandINPIT
PROCESS FOR THE CYCLOADDITION OF A HETERO(ARYL) 1,3-DIPOLE COMPOUND WITH A (HETERO)CYCLOALKYNE
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Paragraph 0357120, (2017/01/26)
A process is provided, comprising reacting a (hetero)aryl 1,3-dipole compound with a (hetero)cycloalkyne, wherein the (hetero)aryl 1,3-dipole compound comprises a 1,3-dipole functional group bonded to a (hetero)aryl group, and wherein the (hetero)aryl 1,3-dipole compound is a (hetero)aryl azide or a (hetero)aryl diazo compound; wherein: (i) the (hetero)aryl group of the (hetero)aryl 1,3-dipole compound comprises a substituent (ii) the (hetero)aryl group of the (hetero)aryl 1,3-dipole compound is an electron-poor (hetero)aryl group and wherein the (hetero)cycloalkyne is a (hetero)cyclooctyne or a (hetero)cyclononyne according to Formula (1). The invention also relates to the products obtainable by the process according to the invention.