30361-31-0

Basic information

• Product Name: 2,4-Hexadienoic acid, methyl ester, (E,Z)-
• CAS NO: 30361-31-0
• Molecular Formula: C7H10O2
• Molecular Weight: 126.155
• Mol File: 30361-31-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2,4-Hexadienoic acid, methyl ester, (E,Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Hexadienoic acid, methyl ester, (E,Z)-(30361-31-0)
• EPA Substance Registry System: 2,4-Hexadienoic acid, methyl ester, (E,Z)-(30361-31-0)

Safety Data

• Hazardous Substances Data: 30361-31-0(Hazardous Substances Data)

Upstream product

• 88418-76-2 5-methyl-2-carbomethoxy-2,5-dihydrothiophene-1,1-dioxide 
• 108965-77-1 (E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-hex-4-enoic acid methyl ester 
• 127280-96-0 Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate 
• 127379-37-7 Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate 
• 127379-38-8 Methyl (cis,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate 
• 186581-53-3 diazomethane 
• 110-44-1 hexa-2,4-dienoic acid 

Downstream Products

• 2527-96-0 methyl 5-methyl-2-furancarboxylate 
• 106369-42-0 methyl 5-methyl-2-selenophenecarboxylate 
• 110318-18-8 4-Methyl-2--1,5-cyclohexadiencarbonsaeure-methylester 
• 110318-19-9 Trimethyl-1,4-diazaspiro<4.5>dec-6-en-6-carbonsaeure-methylester 
• 110434-25-8 cis-1,4,9-Trimethyl-1,4-diazaspiro<4.5>dec-7-en-6-carbonsaeure-methylester 
• 110434-32-7 trans-1,4,9-Trimethyl-1,4-diazaspiro<4.5>dec-7-en-6-carbonsaeure-methylester 
• 110434-34-9 (Z)-3-(1,3-Dimethyl-imidazolidin-2-ylidenemethyl)-hex-4-enoic acid methyl ester 
• 110434-33-8 (E)-3-(1,3-Dimethyl-imidazolidin-2-ylidenemethyl)-hex-4-enoic acid methyl ester 
• 110317-86-7 cis-2-Hydroxy-3,4-dimethyl-1,5-cyclohexadien-1-carbonsaeure-methylester 
• 110317-87-8 trans-2-Hydroxy-3,4-dimethyl-1,5-cyclohexadien-1-carbonsaeure-methylester 
• 110317-84-5 cis-4,5-Dimethyl-6-oxo-1-cyclohexen-1-carbonsaeure-methylester 
• 110317-85-6 trans-4,5-Dimethyl-6-oxo-1-cyclohexen-1-carbonsaeure-methylester 

Relevant articles and documents

Studies on the biological activities of islandic acid and related compounds

-

Stereoselective Synthesis of (2E,4E)- and (2Z,4E)-2,4-Alkadienoates by the Ester Enolate Claisen Rearrangement of (E)-1-Alkyl-3-trimethylsilyl-2-propenyl Glycolates Followed by the Peterson Reaction

The ester enolate Claisen rearrangement of (E)-1-alkyl-3-trimethylsilyl-2-propenyl glycolates gave (E)-erythro-2-hydroxy-3-trimethylsilyl-4-alkenoates with high diastereoselectivity, which were stereoselectively converted into (2E,4E)- and (2Z,4E)-2,4-alkadienoates by the Peterson reaction.

SELECTIVE REACTIONS OF THIOLATE ANIONS WITH 4-HYDROXY-E-2-ALKENOIC ESTERS OR 4-METHANESULFONYLOXY-E-2-ALKENOIC ESTERS. SYNTHESIS OF 2-ALKEN-4-OLIDES (Δα,β-BUTENOLIDES) AND E,E-2,4-ALKADIENOIC ESTERS

Methyl 4-hydroxy-E-2-alkenoates prepared from aldehydes in one step, undergo the Michael reactions with thiolate anions to give 4-alkanolide derivatives, which are converted into 2-alken-4-olides.Methyl 4-methanesulfonyloxy-E-2-alkenoates undergo the substitution reactions, and subsequent treatments give methyl E,E-2,4-alkadienoates.