274694-17-6

Basic information

• Product Name: Phosphoramidic dichloride, bis(phenylmethyl)-
• CAS NO: 274694-17-6
• Molecular Formula: C14H14Cl2NOP
• Molecular Weight: 314.151
• Mol File: 274694-17-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphoramidic dichloride, bis(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoramidic dichloride, bis(phenylmethyl)-(274694-17-6)
• EPA Substance Registry System: Phosphoramidic dichloride, bis(phenylmethyl)-(274694-17-6)

Safety Data

• Hazardous Substances Data: 274694-17-6(Hazardous Substances Data)

Upstream product

• 103-49-1 dibenzylamine 

Downstream Products

• 178955-45-8 diethyl [(ethoxydibenzylamino)phosphinyl]methylphosphonate 

Relevant articles and documents

Synthesis of P-chiral enephosphonic acid derivatives

An efficient and convenient synthesis of chiral enephosphonic acid derivatives (enephosphonates, enephosphonamides, enephosphinates) was reported by a two-step procedure involving alkylidenediphosphorylation of nucleophiles followed by a Horner-Emmons olefination. Depending on the selected strategy, the synthesis could be executed according to a one-pot or a twostep reaction sequence. Regioselectivity of Horner-Emmons reaction and 31P-NMR study of diphosphorylated anions were described.