26567-78-2

Basic information

• Product Name: 4-PHENYLAMINO-3-PENTEN-2-ONE 97
• Synonyms: 4-PHENYLAMINO-3-PENTEN-2-ONE 97;4-phenylamino-3-penten-2-one;(Z)-4-anilinopent-3-en-2-one
• CAS NO: 26567-78-2
• Molecular Formula: C₁₁H₁₃NO
• Molecular Weight: 175.23
• Product Categories: C11 to C12;Carbonyl Compounds;Ketones
• Mol File: 26567-78-2.mol
• Article Data: 108

Chemical Properties

• Melting Point: 48-52 °C(lit.)
• Boiling Point: 296.7°C at 760 mmHg
• Flash Point: 121.4°C
• Appearance: /
• Density: 1.059g/cm³
• Vapor Pressure: 0.00141mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: 4-PHENYLAMINO-3-PENTEN-2-ONE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 4-PHENYLAMINO-3-PENTEN-2-ONE 97(26567-78-2)
• EPA Substance Registry System: 4-PHENYLAMINO-3-PENTEN-2-ONE 97(26567-78-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 26567-78-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H13NO/c1-9(8-10(2)13)12-11-6-4-3-5-7-11/h3-8,12H,1-2H3/b9-8-

Upstream product

• 62-53-3 aniline 
• 123-54-6 acetylacetone 
• 6287-35-0 3-phenylaminobut-2-enoic acid ethyl ester 
• 79-04-9 chloroacetyl chloride 
• 64-10-8 phenyl carbamate 
• 16195-91-8 N-cyclohexyl-4-amino-3-penten-2-one 
• 1510707-07-9 C₁₀H₁₇NO 
• 59487-13-7 N-tert-butyl-4-amino-3-penten-2-one 
• 59487-11-5 N-isopropyl-4-amino-3-penten-2-one 
• 3859-41-4 1,3-cyclopentadione 
• 85143-85-7 4-(1-imidazolyl)-3-penten-2-one 
• 57984-70-0 Pent-3-yn-2-ol 
• 21139-18-4 4,6-dimethyl-1-phenyl-2-oxopyrimidine 
• 85143-87-9 1-(4-oxo-2-penten-2-yl)-3-methylimidazolium iodide 

Downstream Products

• 14627-91-9 4-anilino-pent-3-en-2-one-phenylimine; hydrochloride 
• 1198-37-4 2,4-dimethylquinoline 
• 144175-09-7 7-Hydroxy-7-phenyl-2-(N-phenylamino)hept-2-en-4-one 
• 188558-00-1 (Z)-4-Phenylamino-1-trimethylsilanyl-pent-3-en-2-one 
• 827-69-0 (E)-4-phenyl-3-penten-2-one 
• 587-65-5 N-chloroacetyl-aniline 
• 361437-09-4 4-Chloro-2-[4-(4-fluorophenoxy)phenyl]-6-methylpyridine 
• 361437-11-8 2-[4-(4-fluorophenoxy)phenyl]-4-methoxy-6-methylpyridine 
• 361437-13-0 4-Methoxy-6-[4-(4-fluorophenoxy)phenyl]pyridine-2-carboxylic acid methyl ester 
• 361437-12-9 4-Methoxy-6-[4-(4-fluorophenoxy)phenyl]pyridine-2-carboxylic acid 

Relevant articles and documents

Passerini/tsuji–trost strategy towards pyrrole derivatives

The Passerini reaction of α,β-unsaturated aldehydes affords suitable substrates for a Tsuji–Trost reaction with NH-enamines. The latter behave as a 1,3-bisnucleophile, which leads to the formation of pyrrole derivatives with five points of diversity through a Tsuji–Trost/Michael addition/aromatization cascade.

Metal coordination compound, intermediate, preparation method and application thereof

The invention discloses a metal coordination compound, an intermediate, a preparation method and application thereof, and provides a metal coordination compound I, which can be independently used forcatalyzing ethylene homopolymerization or used for catal

A novel and reusable magnetic nanocatalyst developed based on graphene oxide incorporated strontium nanoparticles for the facial synthesis of β-enamino ketones under solvent-free conditions

A novel magnetic SrFeGO nanocatalyst (NC) was synthesized through a simple sol–gel technique by introducing strontium and iron oxide nanoparticles onto graphene. The synthesized NC was characterized using FT-IR and FE-SEM. Subsequently, the catalytic activity of SrFeGO was tested in a reaction between β-dicarbonyl compounds and aniline derivatives to gain β-enamino ketone derivatives under solvent-free conditions. It was found that SrFeGO NC is a potential catalyst for the synthesis of β-enamino ketones. The β-enamino ketone produced by such reactions could be isolated in high purity without the need for chromatographic purifications. The newly prepared magnetic graphene oxide nanocomposite could be recovered and reused for numerous times with no significant decrease in efficiency. Moreover, the protocol has the advantages of excellent yielding (up to 98%) in short a reaction time, benefitting an easy workup procedure and being environmentally friendly.

Metal complex, intermediate, and preparation method and application of metal complex and intermediate

The invention discloses a metal complex, an intermediate, and a preparation method and application of the metal complex and intermediate. The metal complex I can be used for catalyzing ethylene homopolymerization independently or under action of a cocatal