25779-26-4

Basic information

• Product Name: 2,5-Cyclohexadiene-1,4-dione, 2,3,5-tribromo-
• CAS NO: 25779-26-4
• Molecular Formula: C6HBr3O2
• Molecular Weight: 344.785
• Mol File: 25779-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1,4-dione, 2,3,5-tribromo-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1,4-dione, 2,3,5-tribromo-(25779-26-4)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1,4-dione, 2,3,5-tribromo-(25779-26-4)

Safety Data

• Hazardous Substances Data: 25779-26-4(Hazardous Substances Data)

Upstream product

• 14400-94-3 2,3,4,6-tetrabromophenol 
• 23149-36-2 2,3,5-tribromo-1,4-dihydroxybenzene 
• 89883-16-9 2,3,6-tribromo-4-hydroxy-4-methylcyclohexa-2,5-dienone 
• 1633-14-3 2,5-dibromo-1,4-benzoquinone 
• 14753-51-6 2,5-dibromohydroquinone 
• 14401-61-7 2,4,5-tribromophenol 
• 108-95-2 phenol 
• 106-51-4 p-benzoquinone 
• 583-69-7 2-bromobenzene-1,4-diol 
• 3958-82-5 2-bromo-1,4-benzoquinone 
• 608-71-9 Pentabromophenol 
• 591-20-8 3-Bromophenol 
• 7664-93-9 sulfuric acid 
• 50586-69-1 2,3,6-tribromo-4-chloro-phenol 

Downstream Products

• 488-48-2 tetrabromobenzoquinone 
• 4370-59-6 bromanilic acid 
• 23149-36-2 2,3,5-tribromo-1,4-dihydroxybenzene 
• 40101-03-9 2,5-dibromohydroquinone diacetate 
• 2641-89-6 2,3,5,6-tetrabromohydroquinone 

Relevant articles and documents

The Nitration of Some Substituted 4-Methylphenols; X-Ray Crystal Structure of (Z)-3-Bromo-5-(bromonitromethylene)furan-2(5H)-one

The nitrations of 2-substituted 4-methyl-6-nitrophenols (1a), (1b) and (1c) give 6-substituted 3-methyl-2-nitro-1,4-benzoquinones (2a), (2b) and (2c).Similar reaction of 2,3-dibromo-4-methyl-6-nitrophenol (5) gives 2,3-dibromo-5-methyl-6-nitro-1,4-benzoquinone (7) and the 4-nitratocyclohexa-2,5-dienone (12).In contrast, 2,3,6-tribromo- (4a) and 2,6-dibromo- (4b) 4-methylphenols give 1,4-benzoquinones with loss of the methyl group.Lactone (18) was formed in the nitration of the 2,6-dibromophenol (4b) and its structure was determined by single-crystal X-ray analysis.