25532-45-0 Usage
Description
16,17-Didehydro-19β-methyl-18-oxayohimban-16-carboxylic acid methyl ester is a complex organic compound belonging to the class of alkaloids. It features a unique molecular structure with a dehydrogenated bond between carbons 16 and 17, a methyl group at the 19β position, and an oxo group at the 18 position. The carboxylic acid group at the 16 position is esterified with a methyl group, which may contribute to its solubility and reactivity in various chemical processes. Its configuration has been confirmed through spectroscopic evidence, providing a better understanding of its molecular structure and potential applications.
Uses
Used in Pharmaceutical Industry:
16,17-Didehydro-19β-methyl-18-oxayohimban-16-carboxylic acid methyl ester is used as a pharmaceutical compound for its potential therapeutic properties. The unique molecular structure of this alkaloid may allow it to interact with specific biological targets, such as receptors or enzymes, which could be beneficial in the development of new drugs for various medical conditions.
Used in Chemical Research:
In the field of chemical research, 16,17-Didehydro-19β-methyl-18-oxayohimban-16-carboxylic acid methyl ester can be used as a starting material or intermediate in the synthesis of other complex organic compounds. Its unique structural features may provide opportunities for further functionalization and modification, leading to the development of novel molecules with diverse applications.
Used in Material Science:
The unique molecular structure of 16,17-Didehydro-19β-methyl-18-oxayohimban-16-carboxylic acid methyl ester may also find applications in material science. Its potential to form specific interactions with other molecules or materials could be exploited in the development of new materials with tailored properties, such as improved mechanical strength, thermal stability, or chemical resistance.
Used in Analytical Chemistry:
As a complex organic compound, 16,17-Didehydro-19β-methyl-18-oxayohimban-16-carboxylic acid methyl ester can be used as a reference material or standard in analytical chemistry. Its unique structure and properties may be useful for calibrating instruments, validating analytical methods, or studying the behavior of similar compounds under various conditions.
Check Digit Verification of cas no
The CAS Registry Mumber 25532-45-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,5,5,3 and 2 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 25532-45:
(7*2)+(6*5)+(5*5)+(4*3)+(3*2)+(2*4)+(1*5)=100
100 % 10 = 0
So 25532-45-0 is a valid CAS Registry Number.
InChI:InChI=1/C21H24N2O3/c1-12-16-10-23-8-7-14-13-5-3-4-6-18(13)22-20(14)19(23)9-15(16)17(11-26-12)21(24)25-2/h3-6,11-12,15-16,19,22H,7-10H2,1-2H3/t12-,15+,16-,19+/m1/s1
25532-45-0Relevant articles and documents
MECHANISM OF THE BIOSYNTHETIC CONVERSION OF GEISSOSCHIZINE TO 19-EPI-AJMALICINE IN CATHARANTHUS ROSEUS
Stoeckigt, J.,Hoefle, G.,Pfitzner, A.
, p. 1925 - 1926 (1980)
Geissoschizine (8) is enzymatically converted to 19-epi-ajmalicine (7) first by oxidation to the 4,21-dehydro-intermediate (4) of the heteroyohimbine pathway followed by cyclisation and stereospecific reduction.
A Radical Cascade Enabling Collective Syntheses of Natural Products
Wang, Xiaobei,Xia, Dongliang,Qin, Wenfang,Zhou, Ruijie,Zhou, Xiaohan,Zhou, Qilong,Liu, Wentao,Dai, Xiang,Wang, Huijing,Wang, Shuqing,Tan, Ling,Zhang, Dan,Song, Hao,Liu, Xiao-Yu,Qin, Yong
supporting information, p. 803 - 816 (2017/06/13)
Natural products have long been important inspirations for the development of chemical methodologies, theories, and technologies, and ultimately, discoveries of new drugs and materials. Chemical syntheses have traditionally yielded individual or small groups of natural products; however, methodology development allowing the synthesis of a large collection of natural products remains scarce. Here, we report an efficient photocatalytic radical cascade method that enables access to libraries of chiral and multiple-ring-fused tetrahydrocarbolinones. The radical cascade can controllably introduce complexity and functionality into products with excellent chemo-, regio-, and diastereoselectivity. The power of this distinct method has been demonstrated by the efficient syntheses of 33 monoterpenoid indole alkaloids belonging to four families.
A Concise Strategy for the Syntheses of Indole Alkaloids of the Heteroyohimboid and Corynantheioid Families. Total Syntheses of (+/-)-Tetrahydroalstonine, (+/-)-Cathenamine, and (+/-)-Geissoschizine
Martin, Stephen F.,Benage, Brigitte,Hunter, James E.
, p. 5925 - 5927 (2007/10/02)
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