2467-12-1

Basic information

• Product Name: Trioctyl borate
• Synonyms: boricacid(h3bo3),trioctylester;trioctylborate;tris(1-octyl)borate;TRI-N-OCTYL BORATE;BORIC ACID TRI-N-OCTYL ESTER;trioctoxyborane;Tri-n-octyl Borate
• CAS NO: 2467-12-1
• Molecular Formula: C₂₄H₅₁BO₃
• Molecular Weight: 398.47
• EINECS: 219-580-3
• Product Categories: B (Classes of Boron Compounds);Boric Acid Esters;Boric Acid Triesters
• Mol File: 2467-12-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 379 °C
• Flash Point: 188 °C
• Appearance: /
• Density: 0.86
• Vapor Pressure: 6.57E-06mmHg at 25°C
• Refractive Index: 1.4350-1.4380
• CAS DataBase Reference: Trioctyl borate(CAS DataBase Reference)
• NIST Chemistry Reference: Trioctyl borate(2467-12-1)
• EPA Substance Registry System: Trioctyl borate(2467-12-1)

Safety Data

• RTECS: ED5630000
• Hazardous Substances Data: 2467-12-1(Hazardous Substances Data)

Usage

Safety Profile

Moderately toxic by ingestion. An eye irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS and BORON COMPOUNDS.

InChI:InChI=1/C24H51BO3/c1-4-7-10-13-16-19-22-26-25(27-23-20-17-14-11-8-5-2)28-24-21-18-15-12-9-6-3/h4-24H2,1-3H3

Upstream product

• 93314-06-8 bis(n-octyloxy)chloroborane 
• 98561-14-9 (n-octyloxy)dichloroborane 
• 124-13-0 Octanal 
• 111-87-5 octanol 
• 98220-98-5 N-(1,3,2-dioxaboryl-2-yl)N-phenyl-N'-t-butylurea 

Downstream Products

• 111-66-0 oct-1-ene 
• 111-87-5 octanol 
• 93314-06-8 bis(n-octyloxy)chloroborane 
• 11113-50-1 boric acid 
• 2425-77-6 2-hexyldecan-1-ol 
• 463-11-6 1-Fluoro-octane 

Relevant articles and documents

Sodium Aminodiboranate, a New Reagent for Chemoselective Reduction of Aldehydes and Ketones to Alcohols

Sodium aminodiboranate (NaNH 2(BH 3) 2, NaADBH) is a new member of the old borane family, which exhibits superior performance in chemoselective reduction. Experimental results show that NaADBH can rapidly reduce aldehydes and ketones to the corresponding alcohols in high efficiency and selectivity under mild conditions. There are little steric and electronic effects on this reduction.

Practical and efficient procedure for the in situ preparation of B-alkoxyoxazaborolidines. Enantioselective reduction of prochiral ketones

A new method for the in situ elaboration of B-alkoxyoxazaborolidines is presented. Their use in the enantioselective reduction of prochiral aromatic ketones provides excellent chemical and optical yields of chiral alcohols.