23721-79-1Relevant articles and documents
INFLUENCE OF ELECTRON-WITHDRAWING SUBSTITIUENTS IN THE OXAPHOSPHOLE RING ON THE AXIAL CONFORMATIONAL TRANSMISSION IN P(V) COMPOUNDS
Vries, N. K. De,Buck, H. M.
, p. 267 - 280 (2007/10/02)
A MNDO and 300-MHz 1H NMR study of some trigonal-bipyramidal (TBP) five-coordinated phosphorus (P(V)) compounds is reported.It is shown by the MNDO calculations that, in the oxaphosphole P(V) TBP compounds 5a-c, the electron distribution in the axial bond