23531-69-3Relevant articles and documents
Modeling the Co-Antioxidant Behavior of Monofunctional Phenols. Applications to Some Relevant Compounds
Amorati, Riccardo,Ferroni, Fiammetta,Pedulli, Gian Franco,Valgimigli, Luca
, p. 9654 - 9658 (2007/10/03)
A study on the regeneration of α-tocopherol (vitamin E) by phenolic co-antioxidants in homogeneous hydrocarbon solution is reported. The behavior of some relevant phenols such as BHA, BHT, and trans-resveratrol appears to be nicely predicted by a model based on the knowledge of kinetic and thermochemical data concerning the various reactants. Despite its good reputation as an antioxidant, trans-resveratrol was found only moderately effective (kinh = 2.0 × 105 M-1 s -1 in chlorobenzene at 303 K) and unable to recycle vitamin E.
Mechanism of Antioxidant Reaction of Vitamin E. Charge Transfer and Tunneling Effect in Proton-Transfer Reaction
Nagaoka, Shin-ichi,Kuranaka, Aya,Tsuboi, Hideki,Nagashima, Umpei,Mukai, Kazuo
, p. 2754 - 2761 (2007/10/02)
In order to shed light on the mechanism of proton-transfer reactions, a kinetic and ab initio study of the antioxidant action (intermolecular proton transfer) of vitamin E derivatives has been carried out.The second-order rate constants (ks's)