22731-27-7

Basic information

• Product Name: Methanesulfonamide, N-(2-benzoylphenyl)-1,1,1-trifluoro-
• CAS NO: 22731-27-7
• Molecular Formula: C14H10F3NO3S
• Molecular Weight: 329.3
• Mol File: 22731-27-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methanesulfonamide, N-(2-benzoylphenyl)-1,1,1-trifluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonamide, N-(2-benzoylphenyl)-1,1,1-trifluoro-(22731-27-7)
• EPA Substance Registry System: Methanesulfonamide, N-(2-benzoylphenyl)-1,1,1-trifluoro-(22731-27-7)

Safety Data

• Hazardous Substances Data: 22731-27-7(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 117632-84-5 1-((trifluoromethyl)sulfonyl)-1H-benzo[d][1,2,3]triazole 
• 98-80-6 phenylboronic acid 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 2835-77-0 (2-aminophenyl)(phenyl)methanone 

Downstream Products

• 1399086-34-0 (R)-4-hydroxy-2-(3-nitrophenyl)-4-phenyl-1-(trifluoromethylsulfonyl)-1,4-dihydroquinoline-3-carbaldehyde 
• 249613-39-6 N-(2-benzoyl-phenyl)-N-benzyl-C,C,C-trifluoro-methanesulfonamide 
• 249613-40-9 N-(2-benzoyl-phenyl)-C,C,C-trifluoro-N-(2-oxo-2-pyrrolidin-1-yl-ethyl)-methanesulfonamide 

Relevant articles and documents

Denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids

Unprecedented palladium-catalyzed denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids have been realized, which afforded structurally diverse ortho-amino-substituted biaryl and biaryl ketone derivatives. The key to this success is due to the development of a rationally designed strategy to achieve the ring opening of benzotriazoles with a synergistic activating-stabilizing effect, which enables the in situ generation of the corresponding ortho-amino-arenediazonium species. The present work opens up a new avenue to utilize benzotriazoles as synthetic equivalents of ortho-amino-arenediazoniums, which otherwise could not be directly accessed by existing synthetic methods.

Antiinflammatory fluoroalkanesulfonanilides. 3. Other fluoroalkanesulfonamido diaryl systems

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