209795-84-6

Basic information

• Product Name: 1,10-Phenanthroline, 3,8-bis(4-methoxyphenyl)-
• CAS NO: 209795-84-6
• Molecular Formula: C26H20N2O2
• Molecular Weight: 392.457
• Mol File: 209795-84-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,10-Phenanthroline, 3,8-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-Phenanthroline, 3,8-bis(4-methoxyphenyl)-(209795-84-6)
• EPA Substance Registry System: 1,10-Phenanthroline, 3,8-bis(4-methoxyphenyl)-(209795-84-6)

Safety Data

• Hazardous Substances Data: 209795-84-6(Hazardous Substances Data)

Usage

Family

Phenanthroline derivatives

Type of ligand

Bidentate ligand

Common use

Coordination chemistry and catalysis

Application

Chelating agent to form metal complexes

Fields of use

Biochemistry, pharmaceutical development

Structural feature

Presence of 3,8-bis(4-methoxyphenyl) groups

Influence on reactivity

Steric hindrance can affect reactivity and selectivity in chemical reactions and processes

Upstream product

• 100125-12-0 3,8-dibromo-1,10-phenathroline 
• 213596-33-9 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane 
• 5720-07-0 4-methoxyphenylboronic acid 

Downstream Products

• 433287-22-0 3,8-bis-(4-hydroxyphenyl)-2,9-dimethyl-1,10-phenanthroline 
• 269747-60-6 C₁₂H₆N₂(C₆H₄(OCH₂CH₂)2O)2C₆H₃CH₂OC₆H₄C₁₂H₄N₂(CH₃)2C₆H₄OH 
• 225916-44-9 3,8-bis-(4-methoxyphenyl)-2,9-dimethyl-1,10-phenanthroline 
• 225916-41-6 3,8-bis-(4-methoxyphenyl)-2-methyl-1,10-phenanthroline 

Relevant articles and documents

A phen-terpy conjugate whose chelate coordination axes are orthogonal to one another and its zinc complex

A new highly rigid ditopic ligand has been prepared which consists of a terpy fragment connected through its 4′ position to the 3 position of a phen nucleus via a 1,4-phenylene linker. The chemical structure of the presently reported two-chelate ligand is

The Heteroleptic Cu(I) Photosensitizer-Containing 3,8-Disubstituted Phenanthroline: Synthesis, Photophysical Properties and Photocatalytic Hydrogen Evolution from Water

Four novel heteroleptic Cu(I) photosensitizers with 3,8-diaryl-2,9-diisopropyl-1,10-phenanthroline derivatives as electron-donating bidentate N-ligands have been designed and synthesized. The metal copper complexes are studied in light-driven water reduct

Selective and efficient synthesis of di-, tri- and tetrasubstituted 1,10-phenanthrolines

A general synthetic procedure for the preparation of multisubstituted phenanthrolines is presented. Bromination of 1,10-phenanthroline at the 3 and 8 positions, followed by Suzuki coupling reaction subsequent methylation afford the di-, tri and tetra- substituted phenanthrolines in good yields. These phenanthroline derivatives are useful building blocks in the construction of highly sophisticated molecular architectures.