20364-76-5Relevant articles and documents
Fluorinated thiolates of divalent and trivalent lanthanides. Ln-F bonds and the synthesis of LnF3
Melman,Emge,Brennan
, p. 1078 - 1081 (2001)
Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).
Perfluoromethyl element ligands. XLI. [1] compounds of the type (F3C)2EE′R with pseudohalide character (E = P, As; E′ = S, Se, Te)
Grobe,Vetter
, p. 2085 - 2094 (2008/10/08)
Perfluoromethyl phosphorus and -arsenic compounds of the type (F3C)2EE′R (E = P, As; E′ = S, Se, Te; R = organic group) are prepared either by dismutation (metathesis) of E2(CF3)4 with (RE′)2/su