183007-01-4

Basic information

• Product Name: 2-chloro-3,4-diiodo-5-methylthiophene
• Synonyms: 2-chloro-3,4-diiodo-5-methylthiophene
• CAS NO: 183007-01-4
• Molecular Weight: 384.407
• Mol File: 183007-01-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-3,4-diiodo-5-methylthiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-3,4-diiodo-5-methylthiophene(183007-01-4)
• EPA Substance Registry System: 2-chloro-3,4-diiodo-5-methylthiophene(183007-01-4)

Safety Data

• Hazardous Substances Data: 183007-01-4(Hazardous Substances Data)

Upstream product

• 17249-82-0 2-chloro-5-methylthiophene 

Relevant articles and documents

EPR investigations of β-deuteriated 5,5"-dimethyl-2,2':5',2"-terthiophenes

The unambiguous assignment of the β-hyperfine coupling constants of the radical cations of 5,5"-dimethyl-2,2':5',2"-terthiophene (11) has been achieved by EPR spectroscopic investigations of the deuteriated compounds 12, 13, and 14.The syntheses of these substances were achieved by cross-coupling following the Negishi and Kumada reaction starting from deuteriated derivatives of chloromethylated thiophene derivatives.The generation of the radical cations was carried out by electrochemical oxidation at a constant potential in the EPR spectrometr.In the presence of acidic compounds a D-H exchange at the β-positions of oligothiophenes was observed.The experimentally determined spin density distribution was rationalized by means of semiempirical quantum mechanical calculations (RHF-INDO-SP).Theoretical and experimental assignments are in good agreement.