17104-98-2

Basic information

• Product Name: Benzenemethanol, 4-bromo-a-(nitromethyl)-
• CAS NO: 17104-98-2
• Molecular Formula: C8H8BrNO3
• Molecular Weight: 246.06
• Mol File: 17104-98-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-bromo-a-(nitromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-bromo-a-(nitromethyl)-(17104-98-2)
• EPA Substance Registry System: Benzenemethanol, 4-bromo-a-(nitromethyl)-(17104-98-2)

Safety Data

• Hazardous Substances Data: 17104-98-2(Hazardous Substances Data)

Upstream product

• 75-52-5 nitromethane 
• 1122-91-4 4-bromo-benzaldehyde 
• 586-76-5 4-Bromobenzoic acid 
• 14367-97-6 1-(4-bromophenyl)-2-nitro-1-ethanone 
• 82892-00-0 N-(4-bromobenzoyl)imidazole 
• 873-75-6 4-bromobenzenemethanol 

Downstream Products

• 14367-97-6 1-(4-bromophenyl)-2-nitro-1-ethanone 
• 3156-37-4 (E)-1-bromo-4-(2-nitrovinyl)benzene 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 94768-23-7 N-<1-(4-bromophenyl)-2-nitroethyl>acetamide 

Relevant articles and documents

Method for preparing 2-nitroalkyl-1-alcohol compound and application thereof

The invention relates to a method for preparing a 2-nitroalkane-1-alcohol compound and application thereof, and particularly provides a method for preparing the 2-nitroalkane-1-alcohol compound from iron powder/lead dichloride. The process has the advantages of good yield, high diastereoselectivity, wide functional group tolerance and good compatibility.

Design and development of novel Co-MOF nanostructures as an excellent catalyst for alcohol oxidation and Henry reaction, with a potential antibacterial activity

The novel metal–organic framework Co2(bdda)1.5(OAc)1·5H2O (UoB-3) was synthesized via a simple method at room temperature. UoB-3 was characterized by the different methods, including X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), N2-adsorption/desorption and elemental analysis. The catalytic ability of UoB-3 was detected to be excellent for primary and secondary alcohols oxidation reaction with high yields under solvent-free conditions. Moreover, UoB-3 was highly active for Henry reaction of different aldehydes with nitromethane in water as a green solvent. The nanocatalyst can be recycled for five consecutive cycles without losing its activity and structural rigidity. The antibacterial activity of UoB-3 nanostructures towards Gram-negative bacteria, Escherichia coli and Gram-positive bacteria, Bacillus cereus was also evaluated by using an inhibition zone test. These nanostructures exhibited strong antibacterial effect against both of them. The purpose of this study was the developing metal–organic framework materials with the enhanced activity in various fields.

Copper-bearing chirality helical coordination polymer and preparation method and application thereof

The invention discloses a copper-bearing chirality helical coordination polymer and a preparation method and application thereof. The chemical formula is {[Cu (R,R-cdpa) (H2O)2].2NO3. 2H2O}. The preparation method comprises the steps of adding 5 mL of methanol solution into copper dinitrate-water(1/3) and R,R-cdpa to be mixed to obtain suspension liquid and enabling the suspension liquid to stand at room temperature to obtain the copper-bearing chirality helical coordination polymer. The copper-bearing chirality helical coordination polymer has the advantages that a double chelate ligand R,R-cdpa based on chiraity cyclohexanediamine and Cu (II) are utilized to prepare a one-dimensional helical coordination polymer, and the coordination polymer has a right hand 31 helical structure and has second-order non-linear optical activity. The preparing technology is simple, a complex synthesis device is not needed, the production cost is reduced, and the prepared coordination polymer can be applied to asymmetric Henry reaction of aromatic aldehyde and nitromethane.