166328-07-0Relevant articles and documents
Electrochemical ipso-Thiocyanation of Arylboron Compounds
Dyga, Marco,Hayrapetyan, Davit,Rit, Raja K.,Goo?en, Lukas J.
supporting information, p. 3548 - 3553 (2019/04/26)
An operationally simple electrochemical method for the transition-metal-free ipso-thiocyanation of arylboronic acids and aryl trifluoroborates has been developed. The SCN electrophile is generated in situ by anodic oxidation of thiocyanate anions, which avoids formation of salt waste and prevents unwanted side reactions arising from chemical oxidants. The reaction proceeds regiospecifically, and the scope extends to non-activated aromatic systems. (Figure presented.).
Alkali metal salts with designable aryltrifluoroborate anions
Iwasaki, Kazuki,Yoshii, Kazuki,Tsuzuki, Seiji,Matsumoto, Hajime,Tsuda, Tetsuya,Kuwabata, Susumu
, p. 9468 - 9476 (2016/10/30)
Aryltrifluoroborate ([ArBF3]-) has a designable basic anion structure. Various [ArBF3]--based anions were synthesized to create novel alkali metal salts using a simple and safe process. Nearly 40 novel alkali metal salts were successfully obtained, and their physicochemical characteristics, particularly their thermal properties, were elucidated. These salts have lower melting points than those of simple inorganic alkali halide salts, such as KCl and LiCl, because of the weaker interactions between the alkali metal cations and the [ArBF3]- anions and the anions' larger entropy. Moreover, interestingly, potassium cations were electrochemically reduced in the potassium (meta-ethoxyphenyl)trifluoroborate (K[m-OEtC6H4BF3]) molten salt at 433 K. These findings contribute substantially to furthering molten salt chemistry, ionic liquid chemistry, and electrochemistry.
Synthesis of 1-naphthol via oxidation of potassium 1- naphthyltrifluoroborate
Molander, Gary A.,Siddiqui, Sabahat Zahra,Fleury-Brégeot, Nicolas
, p. 153 - 163 (2014/04/03)
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