154905-69-8

Basic information

• Product Name: 3,5-Decanediol, 1-(4-hydroxy-3-methoxyphenyl)-, (3R,5S)-
• CAS NO: 154905-69-8
• Molecular Formula: C17H28O4
• Molecular Weight: 296.407
• Mol File: 154905-69-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3,5-Decanediol, 1-(4-hydroxy-3-methoxyphenyl)-, (3R,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Decanediol, 1-(4-hydroxy-3-methoxyphenyl)-, (3R,5S)-(154905-69-8)
• EPA Substance Registry System: 3,5-Decanediol, 1-(4-hydroxy-3-methoxyphenyl)-, (3R,5S)-(154905-69-8)

Safety Data

• Hazardous Substances Data: 154905-69-8(Hazardous Substances Data)

Upstream product

• 39886-76-5 [6]-gingerol 
• 1606143-55-8 C₁₄H₂₄O₄ 
• 1606143-53-6 C₁₄H₂₆O₆ 
• 1606143-52-5 C₁₇H₃₀O₆ 
• 1606143-54-7 C₁₆H₃₀O₁₀S₂ 
• 371972-57-5 C₁₉H₃₀O₅ 
• 676456-67-0 (3S)-3-{[1-(tert-butyl)-1,1-dimethylsilyl]oxy}octanal 
• 144735-54-6 1-ethynyl-4-(benzyloxy)-3-methoxybenzene 
• 35192-73-5 (S)-4-hydroxy-1-nonene 
• 66-25-1 hexanal 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 1360109-84-7 (S)-tert-butyldimethyl(non-1-en-4-yloxy)silane 
• 1360109-87-0 (5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-1-(4-hydroxy-3-methoxyphenyl)decan-3-one 
• 1360109-85-8 C₃₀H₄₄O₄Si 

Downstream Products

• 1360109-93-8 (3R,5S)-1-(4-(benzyloxy)-3-methoxyphenyl)decane-3,5-diyl diacetate 
• 863780-90-9 (3R,5S)-1-(3,4-dimethoxyphenyl)decane-3,5-diyl diacetate 
• 53254-51-6 (3R,5S)-1-(4-hydroxy-3-methoxyphenyl)decane-3,5-diyl diacetate 
• 39886-90-3 (3R,5S)-3,5-Diacetoxy-1-(3-methoxy-4-acetoxyphenyl)decane 

Relevant articles and documents

New sesquiterpenoids from Lycianthes marlipoensis

Two new sesquiterpenoids and one derivative, lycifuranone A (= (4R)-4,5-dihydro-4-(3-hydroxy-2,6-dimethylbenzyl)-5,5-dimethylfuran-2(3H)-one; 1), lycifuranone B (= 4,5-dihydroxy-3-methyl-2-1{[(3R)-tetra-hydro-2,2-dimethyl- 5-oxofuran-3-yl]methyl} benzaldehyde; 2), and lycifuranone C (= (4R)-4-(3,4-dihydroxy-6-{(2S,4R,6S)-4-[2-(4-hydroxy-3-methoxyphenyl)ethyl] -6-pentyl[1,3]dioxan-2-yl}-2-methylbenzyl)-4,5-dihydro-5,5-dimethylfuran-2(3H) -one; 3), respectively, have been isolated from the roots of Lycianthes marlipoensis, and their structures were established by spectroscopic methods.

A chiral pool and cross metathesis based synthesis of gingerdiols

Both (3R,5S)- and (3R,5R)-gingerdiols were synthesized. Their 1,3-diol motifs were derived from enantiopure epoxy chiral building blocks that were readily accessible from D-gluconolactone. The effect of deuterating the OH groups of the natural isomer on its optical rotation was also examined. In the course of the syntheses of the targets, an unexplored cross-metathesis (CM) reaction of unprotected 5-substituted pent-1-ene-3,5-diols was investigated, in which the CM product readily underwent an allylic epimerization and oxidation, as the starting diols rearranged into ketones with unprecedented ease. These problems were eventually resolved by performing the CM reaction in toluene in the presence of phenol. The cause of these unexpected, yet very interesting phenomena, was determined to be the presence of the unprotected OH group at C-5 of the 5-substituted pent-1-ene-3,5-diol. A mechanistic rationale is also presented. Copyright

A new method for the demetallation of tricarbonyliron diene complexes by total hydrogenation with Raney nickel. Application to a very short synthesis of (+)-[6]-gingerdiol

Demetallation of tricarbonyliron diene complexes is rapidly achieved by treatment with freshly prepared Raney nickel. The ligands which are totally hydrogenated during the decomplexation are easily isolated in high yields, without racemization, if chiral.