15450-93-8

Basic information

• Product Name: 1H-Phosphole, 2,5-dihydro-3-methyl-1-phenyl-
• CAS NO: 15450-93-8
• Molecular Formula: C11H13P
• Molecular Weight: 176.198
• Mol File: 15450-93-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1H-Phosphole, 2,5-dihydro-3-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Phosphole, 2,5-dihydro-3-methyl-1-phenyl-(15450-93-8)
• EPA Substance Registry System: 1H-Phosphole, 2,5-dihydro-3-methyl-1-phenyl-(15450-93-8)

Safety Data

• Hazardous Substances Data: 15450-93-8(Hazardous Substances Data)

Usage

Chemical compound

1H-Phosphole, 2,5-dihydro-3-methyl-1-phenyl-

Structure

Contains a phosphole ring and a phenyl group attached

Composition

Contains phosphorus, carbon, and hydrogen atoms

Properties

Heterocyclic compound with interesting properties

Applications

Potential use in organic synthesis and as an intermediate in chemical production

Target for research

Unique structure and reactivity make it an interesting target for further exploration in phosphorus chemistry

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 78-79-5 isoprene 
• 7564-51-4 2,5-dihydro-3-methyl-1-phenyl-1H-phosphole 1-oxide 
• 39834-66-7 1-bromo-3-methyl-3-phospholene 
• 17786-50-4 1-bromo-3-methyl-1-phenyl-2,5-dihydro-1H-phospholium; bromide 

Downstream Products

• 15450-94-9 1-benzyl-3-methyl-1-phenyl-2,5-dihydro-1H-phospholium; bromide 
• 143924-62-3 cis-4,5-dimethyl-1,2-diphenyl-1,2,3,6-tetrahydro-1,2-diphosphinine 
• 143924-62-3 trans-4,5-dimethyl-1,2-diphenyl-1,2-diphosphacyclohex-4-ene 
• 14409-95-1 1-phenyl-3,4-dimethyl-2,5-dihydro-1H-phosphole 
• 2290-06-4 phenylphosphinidene 
• 2176-06-9 diphenyldiphosphene 
• 78-79-5 isoprene 
• 179989-97-0 1-phenyl-2,5-dihydro-3-methyl-1H-phosphole-1-borane 
• 14463-05-9 1,2-Diphenyl-4,5-dimethyl-tetrahydro-1,2-diphosphinin 
• 832-01-9 methyl p-methoxycinnamate 
• 103-26-4 methyl cinnamate 
• 637-57-0 methyl 4-nitrocinnamate 

Relevant articles and documents

Isomerization and application of phospholene oxides

In this research, an investigation of the isomerization and the applications of 3-phospholene oxides were elaborated. The isomerization of 3-phospholene oxides to 2-phospholene oxides was investigated under thermal condition. The application of bases and acids was also tested in this reaction. Moreover, the isomerization was also elaborated via the formation of halophosphonium salt intermediates. The 3-phospholene oxides were deoxygenated and transformed to the corresponding palladium complexes.

A new family of platinum(ii) complexes incorporating five-and six-membered cyclic phosphine ligands

New platinum complexes of the type cis-Pt(L)2Cl2 have been synthesized from five-and six-membered cyclic phosphines, which were prepared after deoxygenating a series of phosphine oxides (3-phospholene oxides, phospholane oxides, a 1,

General Approaches to Phosphinidenes via Retroadditions

The retroaddition strategy for the generation of phosphinidenes involves thermal and photochemical decomposition of 1-arylphosphiranes and photolysis of 1-aryl-3-phospholenes.Evidence that free phosphinidenes are produced as reactive intermediates includes a lack of dependence of the conversion rate on precursor and substrate concentrations and the nature of the reaction products.These are best rationalized by the addition of phosphinidenes to carbon-carbon ?-bonds forming three-membered rings and the dimerization of phosphinidenes to diphosphenes.