1544138-11-5Relevant articles and documents
A catalyst- And additive-free synthesis of alkoxyhydrosiloxanes from silanols and alkoxyhydrosilanes
Fuchise, Keita,Igarashi, Masayasu,Nozawa, Takeshi,Sato, Kazuhiko,Satoh, Yasushi
supporting information, p. 8218 - 8221 (2020/08/17)
A convenient method for the selective synthesis of alkoxyhydrosiloxanes that bear SiH and SiOR2 groups on the same silicon atom, R13Si-O-SiR32-n(OR2)nH (n = 0, 1, or 2), via a simple catalyst- and additive-free dealcoholization reaction between silanols and alkoxyhydrosilanes has been developed. These alkoxyhydrosiloxanes can be easily converted into Si(OR2)3-containing siloxanes by zinc catalyzed alkoxylation and alkoxy-containing silphenylene polymers by platinum catalyzed hydrosilylation. This journal is
