152932-57-5Relevant articles and documents
Direct Difluoromethylation of Aryl Halides via Base Metal Catalysis at Room Temperature
Xu, Long,Vicic, David A.
supporting information, p. 2536 - 2539 (2016/03/12)
A stable and isolable difluoromethyl zinc reagent has been prepared through the reaction of ICF2H with diethyl zinc and DMPU. This new zinc reagent is a free-flowing solid and can be used in combination with a nickel catalyst to difluoromethylate aryl iodides, bromides, and triflates at room temperature. Such mild conditions for the catalytic difluoromethylation of these substrates are unprecedented.
3,4-Di-substituted cyclobutene-1,2-diones as CXC-chemokine receptor ligands
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Page 125, (2008/06/13)
There are disclosed compounds of the formula or a pharmaceutically acceptable salt or solvate thereof which are useful for the treatment of chemokine-mediated diseases such as acute and chronic inflammatory disorders and cancer.
Esters of 2,2-dimethyl-3-[(2,2-difluoro-cyclopropylidene) methyl]cyclopropane carboxylic acids
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, (2008/06/13)
A compound selected from the group consisting of all stereoisomeric forms and mixtures thereof of a compound of the formula STR1 wherein Y and Z are individually selected from the groups consisting of hydrogen, halogen, --CF3, alkyl, alkoxy and alkylthio of 1 to 8 carbon atoms and aryl, aryloxy and arylthio of up to 14 carbon atoms optionally substituted with at least one member of the group consisting of halogen, hydroxy optionally esterified etherified, --CF3 and alkyl of 1 to 8 carbon atoms and R is alkyl of 1 to 8 carbon atoms or the remainder of a pyrethrinoid alcohol having excellent pesticidal properties and their preparation and intermediates.