14933-95-0Relevant articles and documents
LDA-promoted decomposition of benzenesulfenamides. A route to aminyl radicals by dioxygen oxidation of lithium amides
Barbieri, Anna,Montevecchi, Pier Carlo,Nanni, Daniele,Navacchia, Maria Luisa
, p. 13255 - 13264 (2007/10/03)
The LDA-promoted decomposition of N-monosubstituted sulfenamides 1a-d occurs through the formation of thioaminyl anions, which undergo oxidation either at sulfur, with formation of sulfonamides, or at nitrogen, with formation of thioaminyl radicals, depending on the nature of the 4'-substituent. The reaction of N,N-disubstituted sulfenamides 1e-h proceeds through the intermediacy of a lithium complex capable of generating aminyl radicals via sulfenyl group transfer to the di-iso-propylamido anion and subsequent aerial oxidation of the resulting lithium amides 3e-h.
Alkyl- and Arylsulfenanilides by Cycloelimination of Propene from N-Aryl-S-isopropyl-sulfimides
Claus, Peter K.,Silbernagel, Waltraud,Franek, Walter,Rieder, Werner
, p. 841 - 850 (2007/10/02)
A series of N-aryl-S-isopropyl-S-alkyl- or aryl-sulfimides has been prepared and transformed into alkyl- or arylsulfenanilides, respectively, by thermal cycloelimination of propene. - Keywords: Sulfimides; Sulfenanilides; Thermolysis; Cycloelimination.