14629-97-1

Basic information

• Product Name: Germane, trimethyl(2-phenylethenyl)-
• CAS NO: 14629-97-1
• Molecular Formula: C11H16Ge
• Molecular Weight: 220.838
• Mol File: 14629-97-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Germane, trimethyl(2-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Germane, trimethyl(2-phenylethenyl)-(14629-97-1)
• EPA Substance Registry System: Germane, trimethyl(2-phenylethenyl)-(14629-97-1)

Safety Data

• Hazardous Substances Data: 14629-97-1(Hazardous Substances Data)

Upstream product

• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 993-52-2 hexamethyldigermane 
• 622-25-3 1-(2-chlorovinyl)benzene 
• 76054-64-3 7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-germanorbornadiene 
• 103-64-0 bromostyrene 
• 113352-24-2 PhCHCHGeMe₂GeMe₃ 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 1066-37-1 trimethylbromogermane 
• 30094-01-0 (E)-(2-phenylethenyl)magnesium bromide 

Relevant articles and documents

Palladium-Catalyzed Germylation of Aryl Bromides and Aryl Triflates Using Hexamethyldigermane

Palladium-catalyzed germylation of aryl bromides and aryl triflates using commercially available hexamethyldigermane is described. Optimized reaction conditions afforded various functionalized aryltrimethylgermanes, including drug-like molecules, in moderate to good yields, demonstrating the versatility of the presented protocols.

A First Palladium-Catalyzed Aryldegermylation of Styryltrimethylgermanes

Both β-(E)- and β-(Z)-styryltrimethylgermanes easily reacted with arenediazonium tetrafluoroborates under palladium catalysis to give aryldegermylated products, (E)-PhCH=CHAr and Ph(Ar)C=CH2.On the other hand, the aryldegermylation of α-styrylgermane gave (E)-stilbene derivates with high stereo- and regioselectivities.