14562-02-8 Usage
Description
(4-Nitrophenylimino)triphenylphosphorane is a complex organic compound that consists of a phosphorus atom bonded to three phenyl groups and an imino group with a nitro group attached to a phenyl ring. (4-Nitrophenylimino)triphenylphosphorane is known for its reactivity, particularly in the formation of carbon-nitrogen and carbon-carbon bonds, making it a valuable tool in organic chemistry for creating a diverse range of chemical compounds.
Uses
Used in Organic Synthesis:
(4-Nitrophenylimino)triphenylphosphorane is used as a reagent in organic synthesis for the preparation of imines and related compounds. Its reactive imino group allows it to participate in various chemical reactions, contributing to the formation of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (4-Nitrophenylimino)triphenylphosphorane is used as a key intermediate in the synthesis of various pharmaceutical compounds. Its ability to form carbon-nitrogen and carbon-carbon bonds makes it instrumental in the development of new drugs and medicinal agents.
Used in Chemical Research:
(4-Nitrophenylimino)triphenylphosphorane is also utilized in chemical research for studying the reactivity and properties of imino groups and their potential applications in the synthesis of novel compounds. This helps researchers to better understand the underlying chemical mechanisms and develop new synthetic strategies.
Check Digit Verification of cas no
The CAS Registry Mumber 14562-02-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,6 and 2 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14562-02:
(7*1)+(6*4)+(5*5)+(4*6)+(3*2)+(2*0)+(1*2)=88
88 % 10 = 8
So 14562-02-8 is a valid CAS Registry Number.
InChI:InChI=1/C24H19N2O2P/c27-26(28)21-18-16-20(17-19-21)25-29(22-10-4-1-5-11-22,23-12-6-2-7-13-23)24-14-8-3-9-15-24/h1-19H
14562-02-8Relevant articles and documents
Vinyltriphenylphosphonium salt mediated serendipitous synthesis of aryliminophosphoranes
Yavari, Issa,Adib, Mehdi,Hojabri, Leila
, p. 7213 - 7219 (2002)
Crystalline phosphorus ylides are obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine, dimethyl acetylenedicarboxylate and aromatic amines, such as aniline, 1-naphthylamine, p-toluidine, 4-bromoaniline, 4-nitroaniline, 4-acetylaniline, 2-aminopyridine, or 2-amino-5-bromopyridine. These stabilized phosphoranes undergo a smooth intramolecular reaction in boiling p-xylene or toluene to produce aryliminophosphoranes in excellent yields.
Synthesis and structures of substituted triphen-yl(phenyl-imino)phospho- ranes
De Borger, Roeland,Collas, Alain,Dommisse, Roger,Blockhuys, Frank
experimental part, p. o50-o54 (2010/06/15)
Three substituted triphen-yl(phenyl-imino)phospho-ranes, namely (4-cyano-phenyl-imino)triphenyl-phospho-rane, C25H19N 2P, (I), (4-nitro-phenyl-imino)triphenyl-phospho-rane, C 24H19N2O2P, (II), and (3-nitro-phenyl-imino)triphenyl-phospho-rane, C24H19N 2O2P, (III), were synthesized as precursors for the preparation of substituted diphenyl-carbodiimides. All three compounds display a supramolecular arrangement in which the substituted benzene rings are organized in an antiparallel fashion. The nitro group on the ring participates in C - H...O and O...π inter-actions, forming inter-molecular dimers. Compound (III) shows disorder which involves the rotation of one of the phenyl rings of the triphenyl-phosphine group.
PHOSPHORYLATION OF HETEROCYCLIC COMPOUNDS III. REACTIONS OF PHOSPHORYLATED 2,2,2,5-TETRAPHENYL-Δ4-1,3,4,2λ5-OXADIAZAPHOSPHOLINE WITH NUCLEOPHILES
Zhmurova, I. N.,Yurchenko, V. G.,Pinchuk, A. M.
, p. 1360 - 1363 (2007/10/02)
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