14310-21-5

Basic information

• Product Name: Benzene, 1-methoxy-4-(2-phenylethyl)-
• Synonyms: Benzene, 1-methoxy-4-(2-phenylethyl)-;1-(4-Methoxyphenyl)-2-phenylethane;1-Methoxy-4-(2-phenylethyl)benzene;1-Methoxy-4-phenethylbenzene;1-Phenethyl-4-methoxybenzene;4-Phenethylanisole
• CAS NO: 14310-21-5
• Molecular Formula: C₁₅H₁₆O
• Molecular Weight: 0
• Mol File: 14310-21-5.mol
• Article Data: 58

Chemical Properties

• Boiling Point: 302.7°Cat760mmHg
• Flash Point: 117.8°C
• Appearance: /
• Density: 1.025g/cm³
• Vapor Pressure: 0.00175mmHg at 25°C
• Refractive Index: 1.56
• CAS DataBase Reference: Benzene, 1-methoxy-4-(2-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(2-phenylethyl)-(14310-21-5)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(2-phenylethyl)-(14310-21-5)

Safety Data

• Hazardous Substances Data: 14310-21-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H16O/c1-16-15-11-9-14(10-12-15)8-7-13-5-3-2-4-6-13/h2-6,9-12H,7-8H2,1H3

Upstream product

• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 
• 6335-83-7 4-(2-phenylethyl)phenol 
• 77-78-1 dimethyl sulfate 
• 94093-86-4 N-benzyl-N-(4-methoxy-benzyl)-hydrazine 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 100-66-3 methoxybenzene 
• 623-12-1 4-chloromethoxybenzene 
• 104-47-2 p-methoxybenzylnitrile 
• 7380-78-1 4-(phenylethynyl)anisole 
• 100-42-5 styrene 
• 14425-64-0 4-methoxyphenethyl bromide 
• 100-59-4 phenylmagnesium chloride 
• 103-82-2 phenylacetic acid 
• 104-01-8 4-Methoxyphenylacetic acid 

Downstream Products

• 6335-83-7 4-(2-phenylethyl)phenol 
• 1023-17-2 4-methoxyphenyl benzyl ketone 
• 5773-56-8 1,2-Diphenylethanol 
• 5422-47-9 1-(4-methoxyphenyl)-2-phenylethan-1-ol 
• 20498-68-4 1-phenyl-2-(4-methylphenyl)ethanol 
• 21511-90-0 N-(1,2-diphenylethyl)acetamide 
• 93652-27-8 1-(4-methoxyphenyl)-2-phenylethyl acetate 
• 100-52-7 benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-51-6 benzyl alcohol 
• 23923-24-2 2,3-bis-(p-methoxyphenyl)-4,5-diphenylcyclopenta-2,4-dienone 
• 23923-26-4 4-Phenyl-2,3,5-tris-(p-anisyl)-(α,α',β)-cyclopentadien-(2,4)-on-(1) 
• 133349-91-4 1-(1-(4-methoxyphenyl)-2-phenylethyl)-1H-benzo[d][1,2,3]triazole 

Relevant articles and documents

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Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis

The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.

Chemoselective Hydrogenation of Alkynes to (Z) -Alkenes Using an Air-Stable Base Metal Catalyst

A highly selective hydrogenation of alkynes using an air-stable and readily available manganese catalyst has been achieved. The reaction proceeds under mild reaction conditions and tolerates various functional groups, resulting in (Z)-alkenes and allylic alcohols in high yields. Mechanistic experiments suggest that the reaction proceeds via a bifunctional activation involving metal-ligand cooperativity.