1421606-38-3

Basic information

• Product Name: (E)-(4-(2-iodovinyl)phenyl)(methyl)sulfane
• Synonyms: (E)-(4-(2-iodovinyl)phenyl)(methyl)sulfane
• CAS NO: 1421606-38-3
• Molecular Weight: 276.141
• Mol File: 1421606-38-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(4-(2-iodovinyl)phenyl)(methyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(4-(2-iodovinyl)phenyl)(methyl)sulfane(1421606-38-3)
• EPA Substance Registry System: (E)-(4-(2-iodovinyl)phenyl)(methyl)sulfane(1421606-38-3)

Safety Data

• Hazardous Substances Data: 1421606-38-3(Hazardous Substances Data)

Upstream product

• 1778-09-2 4-(Methylthio)acetophenone 
• 102016-58-0 p-(methylthio)cinnamic acid 

Downstream Products

• 1421606-68-9 (E)-4-methoxy-N-(4-(methylthio)styryl)quinoline-2-carboxamide 
• 1421606-72-5 (E)-8-chloro-4-ethoxy-N-(4-(methylthio)styryl)quinoline-2-carboxamide 
• 1421606-76-9 (E)-4-ethoxy-8-methoxy-N-(4-(methylthio)styryl)quinoline-2-carboxamide 

Relevant articles and documents

Rhodium-Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation

The rhodium-catalyzed deoxygenation and borylation of ketones with B2pin2 have been developed, leading to efficient formation of alkenes, vinylboronates, and vinyldiboronates. These reactions feature mild reaction conditions, a broad substrate scope, and excellent functional-group compatibility. Mechanistic studies support that the ketones initially undergo a Rh-catalyzed deoxygenation to give alkenes via boron enolate intermediates, and the subsequent Rh-catalyzed dehydrogenative borylation of alkenes leads to the formation of vinylboronates and diboration products, which is also supported by density functional theory calculations.