13894-61-6

Basic information

• Product Name: methyl (E)-hex-3-enoate
• Synonyms: methyl (E)-hex-3-enoate;(E)-3-Hexenoic acid methyl ester;3-Hexenoic acid, methyl ester, (3E)-;3-Hexenoic acid, methyl ester, (E)-;Einecs 237-662-7
• CAS NO: 13894-61-6
• Molecular Formula: C₇H₁₂O₂
• Molecular Weight: 128.16898
• EINECS: 237-662-7
• Mol File: 13894-61-6.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 145.8°Cat760mmHg
• Flash Point: 55.7°C
• Appearance: /
• Density: 0.907g/cm³
• Vapor Pressure: 4.78mmHg at 25°C
• Refractive Index: 1.427
• CAS DataBase Reference: methyl (E)-hex-3-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-hex-3-enoate(13894-61-6)
• EPA Substance Registry System: methyl (E)-hex-3-enoate(13894-61-6)

Safety Data

• Hazardous Substances Data: 13894-61-6(Hazardous Substances Data)

Usage

General Description

Methyl (E)-hex-3-enoate is a chemical compound that belongs to the class of esters. It is commonly found in fruits, such as apples and bananas, and is responsible for their characteristic sweet aroma. methyl (E)-hex-3-enoate is also used as a flavoring agent in food and beverage products, as well as in the production of perfumes and fragrances. Methyl (E)-hex-3-enoate has a fruity and floral scent, making it a popular choice for enhancing the aroma of various consumer products. Additionally, it is also used in the synthesis of other organic compounds and has potential applications in the pharmaceutical and cosmetic industries.

InChI:InChI=1/C7H12O2/c1-3-4-5-6-7(8)9-2/h4-5H,3,6H2,1-2H3/b5-4+

Upstream product

• 67-56-1 methanol 
• 1577-18-0 (E)-3-hexenoic acid 
• 87498-17-7 methyl hex-3-ynoate 
• 124-38-9 carbon dioxide 
• 123-38-6 propionaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 17814-72-1 pent-2-ynecarboxylic acid 
• 74-88-4 methyl iodide 
• 1918-79-2 2-methylthiophene-5-carboxylic acid 
• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 186581-53-3 diazomethane 

Downstream Products

• 6002-99-9 methyl 4-phenylhexanoate 
• 13317-80-1 methyl 5-phenylhexanoate 
• 137360-04-4 4(R*)-tert-Butyldiphenylsilyloxy-5(S*)-ethyl-4,5-dihydro-2(3H)-furanone 
• 137360-02-2 5(R*)-tert-Butyldiphenylsilyloxy-3(R*,S*),6(S*)-dihydroxy-1-octene 
• 137360-01-1 8(R*)-tert-Butyldiphenylsilyloxy-9(S*)-ethyl-4,7,8,9-tetrahydro-2(3H)-oxoninone 
• 137360-05-5 2(R*,S*)-Phenylselenomethyl-4(S*)-ethyl-5(R*)-tert-butyldiphenylsilyloxy-7(R*,S*)-vinyl-1,3-dioxepane 
• 111-27-3 hexan-1-ol 

Relevant articles and documents

Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.

Model studies of the overall 5-endo-trig iodocyclization of homoallylic alcohols

Overall 5-endo-trig iodocyclizations of homoallylic alcohols, with a range of substitution patterns, leading to β-iodotetrahydrofurans are usually highly efficient and stereoselective when carried out in anhydrous acetonitrile in the presence of sodium hydrogen carbonate. Such cyclizations, which are not exceptions to Baldwin's rules as they are electrophile-driven, appear to proceed via a well-ordered chair-like transition state. The iodine can be replaced by hydroxy, acetoxy and azide groups.

Regiochemical control of the ring opening of 1,2-epoxides by means of chelating processes.11. Ring opening reactions of aliphatic mono- and difunctionalized cis and trans 2,3- and 3,4-epoxy esters

The regiochemical outcome of the ring opening of 1,2-epoxides through chelation processes assisted by metal ions, was verified in the azidolysis of simple aliphatic cis and trans 2,3- and 3,4-epoxy esters and in the corresponding derivatives bearing an ether functionality (OBn) in an allylic relationship to the oxirane ring. The results indicate that the behavior of these epoxides is influenced both by the opening conditions (standard or metal-assisted) and the promoting metal salt [LiClO4 or Mg(ClO4)2]. Copyright