137897-48-4

Basic information

• Product Name: Silane, [(3,6-dihydro-2H-pyran-4-yl)oxy]tris(1-methylethyl)-
• CAS NO: 137897-48-4
• Molecular Formula: C14H28O2Si
• Molecular Weight: 256.461
• Mol File: 137897-48-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [(3,6-dihydro-2H-pyran-4-yl)oxy]tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(3,6-dihydro-2H-pyran-4-yl)oxy]tris(1-methylethyl)-(137897-48-4)
• EPA Substance Registry System: Silane, [(3,6-dihydro-2H-pyran-4-yl)oxy]tris(1-methylethyl)-(137897-48-4)

Safety Data

• Hazardous Substances Data: 137897-48-4(Hazardous Substances Data)

Upstream product

• 29943-42-8 Tetrahydro-4H-pyran-4-one 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Relevant articles and documents

Oxidative addition of azide anion to triisopropylsilyl enol ethers: Synthesis of α-azido ketones and 2-amino(methoxycarbonyl)alk-2-en-1-ones

Treatment of triisopropylsilyl enol ethers with ceric ammonium nitrate/sodium azide at -20°C in acetonitrile gives α-azido ketones in average to good yields (50-80%). Subsequent conversion of the α-azido ketones into 2-amino(methoxycarbonyl)cycloalk-2-en-1-ones is described.