137041-63-5

Basic information

• Product Name: Cyclopent[b]indol-3a(1H)-ol, 8b-[(2,6-dichlorophenyl)iminomethyl]-2,3,4,8b-tetrahydro-4-methyl-
• CAS NO: 137041-63-5
• Molecular Formula: C19H18Cl2N2O
• Molecular Weight: 361.271
• Mol File: 137041-63-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopent[b]indol-3a(1H)-ol, 8b-[(2,6-dichlorophenyl)iminomethyl]-2,3,4,8b-tetrahydro-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopent[b]indol-3a(1H)-ol, 8b-[(2,6-dichlorophenyl)iminomethyl]-2,3,4,8b-tetrahydro-4-methyl-(137041-63-5)
• EPA Substance Registry System: Cyclopent[b]indol-3a(1H)-ol, 8b-[(2,6-dichlorophenyl)iminomethyl]-2,3,4,8b-tetrahydro-4-methyl-(137041-63-5)

Safety Data

• Hazardous Substances Data: 137041-63-5(Hazardous Substances Data)

Upstream product

• 2904-62-3 2,6-dichlorobenzonitrile N-oxide 
• 52751-31-2 4-methyl-1,2,3,4-tetrahydro-cyclopenta[b]indole 
• 137041-59-9 3-(2,6-dichlorophenyl)-8,8a-dihydro-8-methyl-3a,8a-propano-3aH-isoxazolo<5,4-b>indole 

Downstream Products

• 137041-62-4 indeno-isoxazolo-indole propellane 
• 137041-64-6 9b-(2,6-dichloro-α-iminobenzyl)-4b-hydroxy-5-methylindeno<1,2-b>indole 
• 1194-65-6 2,6-dichloro-benzonitrile 
• 55366-49-9 N-methyl-1,2,3,4,5,6-hexahydro-1-benzoazocine-2,6-dione 

Relevant articles and documents

Synthesis of Heterocyclic Propellanes by 1,3-Dipolar Cycloaddition of 2,6-Dichlorobenzonitrile Oxide to 2,3-Fused Indoles. Catalytic Hydrogenation of the Cycloadducts

N-Methylcycloalkanoindoles 1a, 1c-d and N-methylindenoindole (1e) react with 2,6-dichlorobenzonitrile oxide (2) to afford regioselectively propellanes 3.Catalytic hydrogenation of compounds 3 proceeds via the labile β-hydroxyimines 4, which are further decomposed to the starting indole and 2,6-dichlorobenzonitrile.In one case the intermediate imine 4e is stable and isolated in pure form. Key Words: Propellanes, heterocyclic / Nitrile oxides / Indoles, 2,3-fused / 1,3-Dipolar cycloaddition