1361954-30-4

Basic information

• Product Name: C₂₇H₂₉NO₅
• Synonyms: C₂₇H₂₉NO₅
• CAS NO: 1361954-30-4
• Molecular Weight: 447.531
• Mol File: 1361954-30-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₉NO₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₉NO₅(1361954-30-4)
• EPA Substance Registry System: C₂₇H₂₉NO₅(1361954-30-4)

Safety Data

• Hazardous Substances Data: 1361954-30-4(Hazardous Substances Data)

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 115-53-7 sinomenine 

Relevant articles and documents

Selective catalytic C-H alkylation of alkenes with alcohols

Alkenes and alcohols are among the most abundant and commonly used organic feedstock in industrial processes. We report a selective catalytic alkylation reaction of alkenes with alcohols that forms a carbon-carbon bond between vinyl carbon-hydrogen (C-H) and carbon-hydroxy centers with the concomitant loss of water. The cationic ruthenium complex [(C6H6)(PCy 3)(CO)RuH]+BF4- (Cy, cyclohexyl) catalyzes the alkylation in solution within 2 to 8 hours at temperatures ranging from 75° to 110°C and tolerates a broad range of substrate functionality, including amines and carbonyls. Preliminary mechanistic studies are inconsistent with Friedel-Crafts-type electrophilic activation of the alcohols, suggesting instead a vinyl C-H activation pathway with opposite electronic polarization.