135103-64-9

Basic information

• Product Name: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-propenyl)-1-cyclohexen-1-yl]oxy]-
• CAS NO: 135103-64-9
• Molecular Formula: C15H28OSi
• Molecular Weight: 252.472
• Mol File: 135103-64-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-propenyl)-1-cyclohexen-1-yl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-propenyl)-1-cyclohexen-1-yl]oxy]-(135103-64-9)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-propenyl)-1-cyclohexen-1-yl]oxy]-(135103-64-9)

Safety Data

• Hazardous Substances Data: 135103-64-9(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 

Relevant articles and documents

A novel nucleophilic substitution of in situ generated 3-tert-butyldimethyl-silyloxyalk-2-enylsulfonium salts with allylindium reagents

(equation presented) In situ generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts derived from the reaction of α,β-enones with dimethyl sulfide in the presence of TBSOTf undergo a novel nucleophilic substitution with in situ generated allylindium reagents from indium and allyl halides to give silyl enol ethers of δ,ε-unsaturated ketones, which correspond to Michael addition products, in good yields. ? Korea Advanced Institute of Science and Technology.

Trialkylsilyl triflate promoted conjugate addition of allylstannes to α,β-enones

Trialkylsilyl triflates promote conjugate additon of allylstannes to α,β-enones to afford β-alkylated silyl enol ethers in high yields.